The design and development of a compact wireless gas sensor with a surface modified multiwalled carbon nanotube (f-CNT) chemiresistor as the sensing element is presented in this paper. f-CNT/polymer composite sensing film is patterned on a printed circuit board and is integrated to the wireless system. The change in resistance of the CNT/polymer composite film due to exposure of different gases is utilized as the principle of this gas sensor. The response for different organic vapors are evaluated and it is observed that the f-CNT/PMMA composite film shows fast response and change in resistance of the order of 10 2-10 3 due to its surface modification.
This paper relates for the first time, multiple resonant frequencies of fractal element antennas using Koch curves to their fractal dimension. Dipole and monopole antennas based fractal Koch curves studied so far have generally been limited to certain standard configurations of the geometry. It is possible to generalize the geometry by changing its indentation angle, to vary its fractal similarity dimension. This variation results in self-similar geometry which can be generated by a recursive algorithm. Such a variation is found to have a direct influence on the input characteristics of dipole antennas. The primary resonant frequency, the input resistance at this resonance, and the ratio of first two resonant frequencies, have all been directly related to the fractal dimension. Curve-fit expressions can also be obtained for the performance of antennas at their primary resonance, in terms of fractal iteration and fractal dimension. The antenna characteristics have been studied using extensive numerical simulations and are experimentally verified. These findings underscore the significance of fractal dimension as an important mathematical property of fractals that can be used as a design parameter for antennas. The use of these ideas would not only reduce the computational intensity of optimization approaches for design of fractal shaped antennas, but also help antenna designers approach the problem systematically. Design formulation for antennas based on other fractal geometries can be similarly obtained after identifying suitable parameters of variation. This would therefore help analytical design of multiband and multifunctional antennas using fractal geometries.Index Terms-Fractals, multifrequency antennas, wire antennas.
The design and development of composite thin films of polymethylmethacrylate (PMMA) with multiwalled carbon nanotubes (CNTs) and surface-modified multiwalled carbon nanotubes (f-CNTs) for gas-sensing applications are presented in this paper. The responses of these composites for different organic vapors were evaluated by monitoring the change in the resistance of thin films of composite when exposed to gases like dichloromethane, chloroform, acetone, methanol, ethyl acetate, toluene and hexane. It was observed that the f-CNT/PMMA composite showed a higher response. There was an increase in resistance of the order of 10 2 -10 3 , due to surface modification, when exposed to dichloromethane, chloroform and acetone. The sensing mechanism is explained on the basis of volume expansion and polar interaction of various vapors on the CNT surface.
A nanocomposite of a multiwalled carbon nanotube and polythiophene was
prepared by functionalizing the nanotube surface with a polythiophene,
poly[3-(2-hydroxyethyl)-2,5-thienylene], containing pendant hydroxyl groups. The
composite was characterized by IR, high resolution TEM and conductivity
measurements. The poly[3-(2-hydroxyethyl)-2,5-thienylene] (PHET) was
synthesized by the oxidation polymerization of 2-(3-thienylethanol) using
FeCl3
and CHCl3. Multiwalled carbon nanotubes were synthesized by a microwave CVD method and
oxidized with potassium permanganate using a phase transfer catalyst in mild conditions.
The COOH groups formed on the nanotube surface were converted to COCl using thionyl
chloride and it was then condensed with the polythiophene at high temperature in
anhydrous DMF. High resolution TEM images showed that the functionalization provided
a firm coating of the conducting polymer on nanotube walls. This nanocomposite with
PHET grafted to CNT showed higher conductivity than a nanocomposite of PHET and
CNT in the same percentage weight composition prepared by ultrasonic mixing of the two.
Such a material was designed and synthesized with a view to electronic and sensor
applications.
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