[reaction: see text] A shape-persistent, conjugated o-phenylene ethynylene cyclic trimer was prepared in one step from tetrasubstituted benzene monomer 4 in 86% isolated yield through precipitation-driven alkyne metathesis. The template-free, selective generation of the molecular triangle 5 is a thermodynamically favored process and under equilibrium control. A novel tetrameric macrocycle 7 was generated via scrambling metathesis between tricycle 5 and hexacycle 6 using this dynamic covalent chemistry.

Large‐area yield prediction early in the growing season is important in agricultural decision‐making. This study derived maize (Zea mays L.) leaf area index (LAI) estimates from spectral data and used these estimates with a simple LAI‐based yield model to forecast yield under irrigated conditions in large areas in Sinaloa, Mexico. Leaf area index was derived from satellite data with the use of an equation developed with LAI measurements from farmers' fields during the 2001–2002 autumn–winter growing season. These measurements were correlated with the normalized difference vegetation index values from 2002 Landsat ETM+ (enhanced thematic mapper) data. The equation was then tested with 2003 Landsat imagery data. A yield model was validated with maximum LAI and yield data measured in farmers' fields in northern and central Sinaloa during three consecutive autumn–winter growing seasons (1999–2000, 2000–2001, and 2001–2002). The yield model was further validated with 2002–2003 autumn–winter ground LAI (gLAI) and satellite‐derived LAI (sLAI) data from 71 farmers' fields in northern and central Sinaloa. Grain yield was predicted with a mean error of −9.2% with maximum gLAI and −11.2% with sLAI. Results indicate that the yield model using LAI can forecast yield in large areas in Sinaloa in the middle of the growing season with a mean absolute error of −1.2 Mg ha−1. The use of sLAI in place of ground measurements increased the mean absolute error by 0.3 Mg ha−1. Nevertheless, the use of sLAI would eliminate laborious LAI measurements for large‐area yield prediction in Sinaloa.

Novel and previously known resistance loci for six phylogenetically diverse viruses were tightly clustered on chromosomes 2, 3, 6 and 10 in the multiply virus-resistant maize inbred line, Oh1VI. Virus diseases in maize can cause severe yield reductions that threaten crop production and food supplies in some regions of the world. Genetic resistance to different viruses has been characterized in maize populations in diverse environments using different screening techniques, and resistance loci have been mapped to all maize chromosomes. The maize inbred line, Oh1VI, is resistant to at least ten viruses, including viruses in five different families. To determine the genes and inheritance mechanisms responsible for the multiple virus resistance in this line, F1 hybrids, F2 progeny and a recombinant inbred line (RIL) population derived from a cross of Oh1VI and the virus-susceptible inbred line Oh28 were evaluated. Progeny were screened for their responses to Maize dwarf mosaic virus, Sugarcane mosaic virus, Wheat streak mosaic virus, Maize chlorotic dwarf virus, Maize fine streak virus, and Maize mosaic virus. Depending on the virus, dominant, recessive, or additive gene effects were responsible for the resistance observed in F1 plants. One to three gene models explained the observed segregation of resistance in the F2 generation for all six viruses. Composite interval mapping in the RIL population identified 17 resistance QTLs associated with the six viruses. Of these, 15 were clustered in specific regions of chr. 2, 3, 6, and 10. It is unknown whether these QTL clusters contain single or multiple virus resistance genes, but the coupling phase linkage of genes conferring resistance to multiple virus diseases in this population could facilitate breeding efforts to develop multi-virus resistant crops.