44 (0)1223 765311 8 9 10Abstract 11 12Several of the emerging technologies for electricity storage are based on some form of thermal energy storage 13

This paper presents a numerical and theoretical analysis of thermal wave propagation in packed bed thermal reservoirs for energy storage applications. In such reservoirs, the range of temperatures encountered is usually such that the solid storage medium will exhibit significant changes in specific heat capacity. This in turn results in non--linear wave propagation and may lead to the formation of shock--like thermal fronts. Such effects have an impact on the exergetic losses due to irreversible heat transfer, and should be taken into account during the design and optimisation of the reservoirs. In the present paper, the emphasis is on thermal losses due to irreversible heat transfer. Frictional (pressure) losses and heat leakage between the storage medium and the environment are also important but are not considered here. The implications of the results for storage material, and particle size are discussed briefly in the context of loss minimisation. Keywords: energy storage, irreversible heat transfer, thermal reservoirs, exergetic loss. NOMENCLATURE

The share of electricity generated by intermittent renewable energy sources is increasing (now at 26% of global electricity generation) and the requirements of affordable, reliable and secure energy supply designate grid-scale storage as an imperative component of most energy transition pathways. The most widely deployed bulk energy storage solution is pumped-hydro energy storage (PHES), however, this technology is geographically constrained. Alternatively, flow batteries are location independent and have higher energy densities than PHES, but remain associated with high costs and short lifetimes, which highlights the importance of developing and utilizing additional larger-scale, longer-duration and long-lifetime energy storage alternatives. In this paper, we review a class of promising bulk energy storage technologies based on thermo-mechanical principles, which includes: compressed-air energy storage, liquid-air energy storage and pumped-thermal electricity storage. The thermodynamic principles upon which these thermo-mechanical energy storage (TMES) technologies are based are discussed and a synopsis of recent progress in their development is presented, assessing their ability to provide reliable and cost-effective solutions. The current performance and future prospects of TMES systems are examined within a unified framework and a thermo-economic analysis is conducted to explore their competitiveness relative to each other as well as when compared to PHES and battery systems. This includes carefully selected thermodynamic and economic methodologies for estimating the component costs of each configuration in order to provide a detailed and fair comparison at various system sizes. The analysis reveals that the technical and economic characteristics of TMES systems are such that, especially at higher discharge power ratings and longer discharge durations, they can offer promising performance (round-trip efficiencies higher than 60%) along with long lifetimes (>30 years), low specific costs (often below 100 $ kWh−1), low ecological footprints and unique sector-coupling features compared to other storage options. TMES systems have significant potential for further progress and the thermo-economic comparisons in this paper can be used as a benchmark for their future evolution.

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