5-hydroxymethylfurfural (HMF) is a suitable platform chemical for the production of useful chemicals and fuels. This study examined the hydrolysis of mixtures of sucrose, glucose and fructose (synthetic sugar cane molasses) and industrial molasses using sulfonated carbon-based heterogeneous catalysts derived from sugar cane bagasse (B-SO3H) and sugar cane molasses (M-SO3H). Microwave heating at 150 °C for 4 h produced 39 mol % HMF yield with B-SO3H on the synthetic sugar solution. The addition of a molasses pretreatment step, as well as, increasing the microwave power was necessary to achieve similar HMF yields with the industrial molasses sample. The hydrolysis of molasses pretreated with formic acid or HCl resulted in a slightly higher HMF yield than the hydrolysis of molasses pretreated with H2SO4. The buffering capacity of the formic acid pretreated molasses was lowered through dilution with water; and subsequently HMF yield was increased to 64.3 mol % (170 °C, 3 h).

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