We demonstrate that superhydrophobic and superoleophobic nanocellulose aerogels, consisting of fibrillar networks and aggregates with structures at different length scales, support considerable load on a water surface and also on oils as inspired by floatation of insects on water due to their superhydrophobic legs. The aerogel is capable of supporting a weight nearly 3 orders of magnitude larger than the weight of the aerogel itself. The load support is achieved by surface tension acting at different length scales: at the macroscopic scale along the perimeter of the carrier, and at the microscopic scale along the cellulose nanofibers by preventing soaking of the aerogel thus ensuring buoyancy. Furthermore, we demonstrate high-adhesive pinning of water and oil droplets, gas permeability, light reflection at the plastron in water and oil, and viscous drag reduction of the fluorinated aerogel in contact with oil. We foresee applications including buoyant, gas permeable, dirt-repellent coatings for miniature sensors and other devices floating on generic liquid surfaces.
Innovations in industrial automation, information and communication technology (ICT), renewable energy as well as monitoring and sensing fields have been paving the way for smart devices, which can acquire and convey information to the Internet. Since there is an ever-increasing demand for large yet affordable production volumes for such devices, printed electronics has been attracting attention of both industry and academia. In order to understand the potential and future prospects of the printed electronics, the present paper summarizes the basic principles and conventional approaches while providing the recent progresses in the fabrication and material technologies, applications and environmental impacts.
Carbon based perovskite solar cells are fabricated for the first time in a room temperature environment by employing inkjet infiltration of perovskite precursor ink. The fabricated perovskite solar cells exhibit impressive performance reproducibility with this automated method and exhibit high stability when exposed to 35 °C for a period of 1046 hours.
Suspension rheology of aqueous coatings
influences the coating application performance at high speeds and
during high rates of change of the shear rate, as well as the quality
of the coated end product determined by the relationship between dewatering,
immobilization, and coating coverage. In the case of paper coatings,
the end-use printing can be significantly affected by the coating
uniformity, pore structure, and surface chemistry. Nanocellulose-containing
materials, such as microfibrillated (MFC) and nanofibrillated (NFC)
cellulose, are potential additives that could at least partly substitute
other natural and synthetic cobinders, including viscoelasticity-inducing
starch, carboxymethyl cellulose (CMC), and polyacrylic thickeners,
in paper-coating color formulations. Work is reported here in which
a systematic comparison of dewatering and rheological characteristics
of coating colors, based on three different pigments and mixtures
thereof, is illustrated using CMC as the cobinder and incorporated
with MFC/NFC as the partial cobinder replacement. All colors are shown
to exhibit viscoelasticity, but the MFC/NFC additives are seen to
operate as water-binding gel-forming components rather than with the
flocculating thickening action of CMC. Immobilization of the color
in the presence of nanofibrillar material is identified as the point
of gel–water entrapment rather than the traditional stick–slip
particle–particle interlocking mechanism predominating in traditional
flocculant thickener formulations.
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