This paper presents a geometry-based statistical model (GBSM) of polarimetric wideband multipath radio channels for vehicle-to-vehicle (V2V) communications. The proposed model captures the effects of depolarization caused by multipath propagation, and it also accounts for the non-stationary characteristics of wideband V2V channels. This is a novel feature, because the existing polarimetric channel models are built on the assumption that the channel is a wide-sense stationary random process. In the modeling framework described in this paper, the channel depolarization function is given by a linear transformation in the form of a simple rotation matrix. This linear transformation is transparent to the polarization of the transmitting and receiving antennas, and to the geometry of the propagation scenario. Compared to other GBSMs for polarimetric V2V channels, the one proposed here is more flexible, and it simplifies the computation of the channel depolarization function.

This paper describes the implementation of a Doppler spectrum measurement platform for narrowband frequency-dispersive vehicle-to-vehicle (V2V) channels. The platform is based on a continuous-wave (CW) channel sounding approach widely used for path-loss and large-scale fading measurements, but whose effectiveness to measure the Doppler spectrum of V2V channels is not equally known. This channel sounding method is implemented using general-purpose hardware in a configuration that is easy to replicate and that enables a partial characterization of frequency-dispersive V2V channels at a fraction of the cost of a dedicated channel sounder. The platform was assessed in a series of field experiments that collected empirical data of the instantaneous Doppler spectrum, the mean Doppler shift, the Doppler spread, the path-loss profile, and the large-scale fading distribution of V2V channels under realistic driving conditions. These experiments were conducted in a highway scenario near San Luis Potosí, México, at two different carrier frequencies, one at 760 MHz and the other at 2,500 MHz. The transmitting and receiving vehicles were moving in the same direction at varying speeds, ranging from 20 to 130 km/h and dictated by the unpredictable traffic conditions. The obtained results demonstrate that the presented measurement platform enables the spectral characterization of narrowband V2V channels and the identification of their Doppler signatures in relevant road-safety scenarios, such as those involving overtaking maneuvers and rapid vehicles approaching the transmitter and receiver in the opposite direction.INDEX TERMS Doppler shift, Doppler spectrum, fading channels, radio-frequency propagation, vehicular communications.

We present extensive density functional theory (DFT) calculations dedicated to analyze the adsorption behavior of CO molecules on small AlxOy (±) clusters. Following the experimental results of Johnson et al. [J. Phys. Chem. A 112, 4732 (2008)], we consider structures having the bulk composition Al2O3, as well as smaller Al2O2 and Al2O units. Our electron affinity and total energy calculations are consistent with aluminum oxide clusters having two-dimensional rhombus-like structures. In addition, interconversion energy barriers between two- and one-dimensional atomic arrays are of the order of 1 eV, thus clearly defining the preferred isomers. Single CO adsorption on our charged AlxOy (±) clusters exhibits, in general, spontaneous oxygen transfer events leading to the production of CO2 in line with the experimental data. However, CO can also bind to both Al and O atoms of the clusters forming aluminum oxide complexes with a CO2 subunit. The vibrational spectra of AlxOy + CO2 provides well defined finger prints that may allow the identification of specific isomers. The AlxOy (+) clusters are more reactive than the anionic species and the final Al2O(+) + CO reaction can result in the production of atomic Al and carbon dioxide as observed from experiments. We underline the crucial role played by the local atomic environment, charge density distribution, and spin-multiplicity on the oxidation behavior of CO molecules. Finally, we analyze the importance of coadsorption and finite temperature effects by performing DFT Born-Oppenheimer molecular dynamics. Our calculations show that CO oxidation on AlxOy (+) clusters can be also promoted by the binding of additional CO species at 300 K, revealing the existence of fragmentation processes in line with the ones experimentally inferred.