Abstract.A new electrical equivalent circuit (EEC) has been proposed to model antiferroelectric liquid crystal devices. This circuit includes a constant phase element to take into account the ferroelectric part of the dielectric response in these devices. Electrical characterization of samples has been carried out using a specific experimental protocol based on impedance spectroscopy. The parameters of waveforms used in impedance measurements have been optimized. The procedure to obtain the components of the EEC has also been explained. Finally, the EEC has been validated by comparing experimental and simulated impedance results. A reasonable agreement between both of them has been obtained in a wide frequency range for all selection voltages. C 2011 Society of Photo-Optical Instrumentation Engineers (SPIE).
Blue viologen-based electrochromic devices on glass substrates were constructed with different internal active layer thickness by means of a thermoplastic spacer (DuPontTM surlyn1702). Optical measurements, chronoamperometry, and cyclic voltammetry (CV) were the techniques used for characterization. Coloration properties such as switching times for coloring and bleaching processes, coloration efficiency, and effective charge density, previously studied for a single device, are now obtained for several devices with different thicknesses. Dependence on thickness in the response times and in voltagedependent parameters of device equivalent electric circuit model was studied in previous works. In this paper, some of those parameters, such as Warburg diffusion, double-layer capacitance, and charge transfer resistance, obtained with electrochemical impedance spectroscopy, are related with the coloration properties and their dependence on the thickness obtained by the aforementioned chronoamperometric and CV characterization.
Visible light communications (VLC) have been proposed for several applications beyond the traditional indoor scenarios, from vehicular to underwater communications. The common element in all these applications is the use of light-emitting diodes (LEDs) in which the forward current that flows through each LED plays a major role. Therefore, knowing the electrical equivalent of the LEDs is a useful tool for the proper design of the VLC systems. Currently, some measurement instruments exist, such as the LCR (inductance, capacitance, and resistance) meters or impedance analyzers to characterize the main parameters of the LEDs. However, these instruments and measurement procedures are subject to satisfying some requirements, such as a minimum value of the input impedance or the maximum forward current. In this work, the LED LXHL-BW02 is used to obtain its equivalent circuit, using different measurement methods and traditional methods of measurement with our proposed method. The equivalent model is implemented on the simulation tool LTSPICE. Our alternative method can be used for determining the electrical equivalent circuit of LEDs subject to high current variations at very high frequencies, in the MHz range, i.e., in an operating range for VLC applications.
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