Sludge dewatering is an important link in sludge treatment. In practical engineering, the dewatering effect of unconditioned sludge is very poor. The use of advanced oxidation technology can improve sludge dewatering performance, reduce sludge capacity, and remove micro-pollutants, which is beneficial for sludge post-treatment and disposal. Based on the current status of sludge conditioning and dehydration, the characteristics of the advanced oxidation method for sludge dehydration were systematically explained using various free radical reaction mechanisms and dehydration conditions. The effects of various advanced oxidation technologies on sludge conditioning and dewatering has been extensively discussed. Finally, the application prospects of the advanced oxidation technology in sludge conditioning and dewatering are presented.

Sludge dewatering is the fundamental process of sludge treatment. Environmentally friendly and efficient sludge conditioning methods are the premises of sludge to achieve dehydration reduction and resource utilization. In response to sewage plant sludge dehydration, fly ash (FA), polymerized aluminum chloride (PAC), and polymer sulfate (PFS) were studied separately to determine their sludge dehydration performance, and the effects of these three conditioner composite regulations on sludge dehydration properties were studied. Compared to the sludge treated only with conditioner, the average particle size of floc increased and the organic matter content in the filtrate decreased. The sludge dewatering efficiency after the conditioning effect is better than that after conditioning a single conditioner. After PFS conditioning with fly ash, the water content and specific resistance (SRF) of the sludge cake can be reduced to 76.39% and 6.63 × 1010 m/kg, respectively. The moisture content and specific resistance (SRF) of the sludge cake can be reduced to 76.10% and 6.91 × 1010 m/kg, respectively. The pH of the sludge and filtrate changed slightly after PAC conditioning with fly ash coupling. These results indicate that fly-ash coupled with PAC and fly-ash coupled with PFS are expected to become a novel and effective environmental protection combined conditioning method for sludge dewatering.