The exploration of new adsorbents
is still highly desirable, especially
those with ultrahigh adsorption capacity, super anti-interference
ability, and excellent regeneration power. Herein, a novel chloromethyl
polystyrene resin supported task-specific ionic liquid adsorbent was
prepared by chemical grafting and its performance to remove p-nitrophenol (PNP) from water was systematically investigated
by both batch process and dynamic column elution method. It was shown
that the adsorbent not only exhibited excellent adsorption performance
toward high concentration PNP with an ultrahigh adsorption capacity
of 1269.8 mg/g within 30 min but also could effectively remove trace
PNP from water at the concentration as low as 0.0025 mg/L. Common
interfering ions and neutral molecules in water, especially K+, Na+, Ca2+, Mg2+, NO3
–, and Cl–, did not interfere
with the removal of PNP even if their concentrations (1 mol/L) were
1 000 000 times higher than that of PNP, which indicates
its potential in removal of PNP from high salinity wastewater. The
adsorbent could be easily regenerated and recycled at least 10 times
with no loss in separation performance. The possible adsorption mechanism
was investigated in various approaches. In addition, the adsorbent
was applied to remove PNP in real water samples, and promising results
were reported.
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