Hydride forming materials, i.e., binary, complex hydrides, and their mixtures, have been extensively investigated owing to their potential hydrogen storage properties. They possess high volumetric hydrogen capacity and relative high gravimetric hydrogen capacity. However, one of the main constraints for their practical application is their slow kinetic behavior. For this reason, enormous effort has been devoted to improve the hydrogenation and dehydrogenation rates. Several strategies have been developed for the enhancement of the kinetic behavior of the most relevant hydride forming materials such as MgH
Several different milling parameters (additive content, rotation velocity, ball-to-powder ratio, degree of filling, and time) affect the hydrogen absorption and desorption properties of a reactive hydride composite (RHC). In this paper, these effects were thoroughly tested and analyzed. The milling process investigated in such detail was performed on the 2LiH-MgB2 system doped with TiCl3. Applying an upgraded empirical model, the transfer of energy to the material during the milling process was determined. In this way, it is possible to compare the obtained experimental results with those from processes at different scales. In addition, the different milling parameters were evaluated independently according to their individual effect on the transferred energy. Their influence on the reaction kinetics and hydrogen capacity was discussed and the results were correlated to characteristics like particle and crystallite size, specific surface area, presence of nucleation sites and contaminants. Finally, an optimal value for the transferred energy was determined, above which the powder characteristics do not change and therefore the RHC system properties do not further improve.
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