Several cubic kilometers of Paleozoic graphite-bearing argillitic country rocks are present as lithic fragments in Bishop Tuff ignimbrite and fallout. The lithics were entrained by the 650 km 3 of rhyolite magma that vented during the 5-to 6-day-long, caldera-forming eruption at Long Valley, California. The caldera is floored by a 350 km 2 roof plate that collapsed during the eruption and consists in large part of the Paleozoic strata that provided the abundant hornfelsed metapelitic lithic clasts in the tuff. Graphite has been identified by Raman spectroscopy, electron-dispersive spectroscopy, and X-ray diffraction as an irregularly dispersed component in the small fraction of Bishop Tuff pumice that is dark-colored. Carbon concentration has been determined in pumice, lithics, and wall rocks. Values of δ 13 C range from -21‰ to -29‰ Vienna Peedee Belemnite (VPDB) for pumice, lithics, and argillitic wall rocks, reflecting the biogenic origin of the reduced carbon in oxygen-limited black Paleozoic marine mudrocks. Carbonate contents, measured separately, are negligible in fresh pumice and lithics. Microprobe analyses of titanomagnetite-ilmenite pairs show that oxygen-fugacity values of numerous batches of postcaldera Early Rhyolite (750-640 ka; ~100 km 3 ) are up to one log unit more reduced than those of the temperature-oxygen fugacity (T-fO 2 ) array of the Bishop Tuff (767 ka), despite similar major-element compositions and Fe-Tioxide temperature ranges. All of the many batches of Early Rhyolite, which erupted episodically over an interval of ~125,000 years, yield the reduced fO 2 values, indicating that reaction with graphite lowered magmatic fO 2 after the caldera-forming eruption but before the first eruption of Early Rhyolite. It is inferred that reaction of postcaldera rhyolite magma with the reduced carbon in a great mass of subsided roof rocks lowered its fO 2 . It is suggested that comparable effects could have attended caldera collapse of other magma chambers hosted in continental sedimentary rocks.
In Mono Basin, California, USA, a near-circular ring fracture 12 km in diameter was proposed by R.W. Kistler in 1966 to have originated as the protoclastic margin of the Cretaceous Aeolian Buttes pluton, to have been reactivated in the middle Pleistocene, and to have influenced the arcuate trend of the chain of 30 young (62−0.7 ka) rhyolite domes called the Mono Craters. In view of the frequency and recency of explosive eruptions along the Mono chain, and because many geophysicists accepted the ring fracture model, we assembled evidence to test its plausibility. The shear zone interpreted as the margin of the Aeolian Buttes pluton by Kistler is 50−400 m wide but is exposed only along a 7-km-long set of four southwesterly outcrops that subtend only a 70° sector of the proposed ring. The southeast end of the exposed shear zone is largely within the older June Lake pluton, and at its northwest end, the contact of the Aeolian Buttes pluton with a much older one crosses the shear zone obliquely. Conflicting attitudes of shear structures are hard to reconcile with intrusive protoclasis. Also inconsistent with the margin of the ovoid intrusion proposed by Kistler, unsheared salients of the pluton extend ∼1 km north of its postulated circular outline at Williams Butte, where there is no fault or other structure to define the northern half of the hypothetical ring. The shear zone may represent regional Cretaceous transpression rather than the margin of a single intrusion. There is no evidence for the Aeolian Buttes pluton along the aqueduct tunnel beneath the Mono chain, nor is there evidence for a fault that could have influenced its vent pattern. The apparently arcuate chain actually consists of three linear segments that reflect Quaternary tectonic influence and not Cretaceous inheritance. A rhyolitic magma reservoir under the central segment of the Mono chain has erupted many times in the late Holocene and as recently as 700 years ago. The ring fracture idea, however, prompted several geophysical investigations that sought a much broader magma body, but none identified a low-density or low-velocity anomaly beneath the purported 12-km-wide ring, which we conclude does not exist.
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