The outstanding journey towards the investigation of mesoporous materials commences with the discovery of high surface area porous silica materials, named MCM-41 (Mobil Composition of Matter-41) according to the inventors’ name Mobile scientists in the United States. Based on a self-assembled supramolecular templating mechanism, the synthesis of mesoporous silica has extended to wide varieties of silica categories along with versatile applications of all these types in many fields. These silica families have some extraordinary structural features, like highly tunable nanoscale sized pore diameter, good Brunauer–Emmett–Teller (BET) surface areas, good flexibility to accommodate different organic and inorganic functional groups, metals etc., onto their surface. As a consequence, thousands of scientists and researchers throughout the world have reported numerous silica materials in the form of published articles, communication, reviews, etc. Beside this, attention is also given to the morphology-oriented synthesis of silica nanoparticles and their significant effects on the emerging fields of study like catalysis, energy applications, sensing, environmental, and biomedical research. This review highlights a consolidated overview of those morphology-based mesoporous silica particles, emphasizing their syntheses and potential role in many promising fields of research.
The vorticity-velocity formulation of the Navier-Stokes equations allows purely kinematical problems to be decoupled from the pressure term, since the pressure is eliminated by applying the curl operator. The Vortex-In-Cell (VIC) method, which is based on the vorticity-velocity formulation, offers particle-mesh algorithms to numerically simulate flows past a solid body. The penalization method is used to enforce boundary conditions at a body surface with a decoupling between body boundaries and computational grids. Its main advantage is a highly efficient implementation for solid boundaries of arbitrary complexity on Cartesian grids. We present an efficient algorithm to numerically implement the vorticity-velocity-pressure formulation including a penalty term to simulate the pressure fields around a solid body. In vorticity-based methods, pressure field can be independently computed from the solution procedure for vorticity. This clearly simplifies the implementation and reduces the computational cost. Obtaining the pressure field at any fixed time represents the most challenging goal of this study. We validate the implementation by numerical simulations of an incompressible viscous flow around an impulsively started circular cylinder in a wide range of Reynolds numbers: Re=40, 550, 3000, and 9500.
To better understand the vortex shedding mechanism and to assess the capability of our numerical methodology, we conducted numerical investigations of vortex shedding from truncated and oblique trailing edges of a modified NACA 0009 hydrofoil. The hybrid particle-mesh method and the vorticity-based subgrid scale model were employed to simulate these turbulent wake flows. The hybrid particle-mesh method combines the vortex-in-cell and the penalization methods. We have implemented numerical schemes to more efficiently use available computational resources. In this study, we numerically investigated vortex shedding from various beveled trailing edges at a Reynolds number of 10 6 . We then compared the numerical results with the experimental data, which show good agreement. We also conducted numerical simulations of wakes behind the hydrofoil at rest in periodically varying flows. Results reveal that vortex shedding is affected by the periodicity of a free-stream flow, as well as the trailing-edge shape.
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