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Based on design thinking of web services network resources, this paper treated the organization and management of web resources as the purpose and built the mathematical model and algorithm of web network resources service. It designed the spiritual home network ideological and political education network system according to model and algorithm. Spiritual home network system achieved three functions. In order to improve the efficiency of network services, this paper matched the service of spiritual home and finally got a simple web service interface. Finally, the paper compared the service system in this paper with the general service system. The service system designed in this paper can search the service needed in a shorter time. Its accuracy is higher than general service system.