Bulk-heterojunction organic solar cells (BHJ-OSCs) have attracted tremendous interest in the scientific community, [1-4] owing to their versatile merits, including transparency, [5] flexibility, [6] solution processability, and light weight. In recent years, extensive efforts have been made to improve the photovoltaic performance, [7-11] which has increased the power conversion efficiency (PCE) by over 18% in binary BHJ-OSCs. [12,13] However, the state-of-art photovoltaic performance of BHJ-OSCs still lags behind other competing photovoltaic technologies, such as silicon-based solar cells [14] and perovskite solar cells. [15] To further elevate the PCE of BHJ-OSCs, integrating two binary OSCs into one ternary OSC has been deemed as one of the most effective approaches. [16-27] By tuning the content of the active layer, ternary BHJ-OSCs, comprising either two donors or two acceptors, can produce a remarkable open-circuit voltage (V OC), short-circuit current density (J SC), and fill factor (FF). Moreover, the unique features observed in intrinsic binary OSCs are likely to be inherited in ternary OSCs. Interestingly, the strategy of ternary OSCs