A novel method of extracting color information on a pixel-by-pixel basis or by the average of the regions of interest (ROIs) from digital images is proposed and demonstrated using newly developed and customized image-processing/analysis software (PicMan). For quantitative and statistical analyses of color, the newly developed software can be used for digital archive or digital forensic applications in various fields. The color differences between unrelated, similar, or identical scenes and or objects were quantified in various formats of desired color spaces such as RGB, HSV, XYZ, CIE L*a*b*, Munsell color, and hexadecimal color values. The color differences were visualized as images of pixel-by-pixel mapping of the DL*, Da*, Db*, DERGB, DEHSV, and DE*L*a*b* values and block comparison images of desired block sizes. Various color analyses and color-difference mapping examples using an aged and damaged oil painting before and after restoration were introduced. The effects of the image file format differences between PNG and JPG on color distortion are demonstrated by statistics and pixel-by-pixel color-difference mapping. A portrait of Chuk-ki Yoo (兪拓基, 1691–1767) on silk from the 18th century from Korea was used for further color analysis for whole and selected areas. A collector’s ownership stamp of Chuk-ki Yoo stamped in red ink on the text areas in one of his book collections was extracted using the image-processing software and superimposed on the original image as a visualization enhancement example. Image analysis, processing, modification, enhancement, and highlighting, as well as statistical color analysis of digital images in most formats, can conveniently and efficiently be performed using one piece of dedicated software (PicMan). The pixel-by-pixel color information extraction and color comparison technique can be very effective for a variety of applications in art and cultural heritage objects.

Colorimetric sensing techniques for point(s), linear and areal array(s) were developed using image sensors and novel image processing software for chemical, biological and medical applications. Monitoring and recording of colorimetric information on one or more specimens can be carried out by specially designed image processing software. The colorimetric information on real-time monitoring and recorded images or video clips can be analyzed for point(s), line(s) and area(s) of interest for manual and automatic data collection. Ex situ and in situ colorimetric data can be used as signals for process control, process optimization, safety and security alarms, and inputs for machine learning, including artificial intelligence. As an analytical example, video clips of chromatographic experiments using different colored inks on filter papers dipped in water and randomly blinking light-emitting-diode-based decorative lights were used. The colorimetric information on points, lines and areas, with different sizes from the video clips, were extracted and analyzed as a function of time. The video analysis results were both visualized as time-lapse images and RGB (red, green, blue) color/intensity graphs as a function of time. As a demonstration of the developed colorimetric analysis technique, the colorimetric information was expressed as static and time-series combinations of RGB intensity, HSV (hue, saturation and value) and CIE L*a*b* values. Both static and dynamic colorimetric analysis of photographs and/or video files from image sensors were successfully demonstrated using a novel image processing software.

Image-based colorimetry has been gaining relevance due to the wide availability of smart phones with image sensors and increasing computational power. The low cost and portable designs with user-friendly interfaces, and their compatibility with data acquisition and processing, are very attractive for interdisciplinary applications from art, the fashion industry, food science, medical science, oriental medicine, agriculture, geology, chemistry, biology, material science, environmental engineering, and many other applications. This work describes the image-based quantification of color and its machine vision and offline applications in interdisciplinary fields using specifically developed image analysis software. Examples of color information extraction from a single pixel to predetermined sizes/shapes of areas, including customized regions of interest (ROIs) from various digital images of dyed T-shirts, tongues, and assays, are demonstrated. Corresponding RGB, HSV, CIELAB, Munsell color, and hexadecimal color codes, from a single pixel to ROIs, are extracted for machine vision and offline applications in various fields. Histograms and statistical analyses of colors from a single pixel to ROIs are successfully demonstrated. Reliable image-based quantification of color, in a wide range of potential applications, is proposed and the validity is verified using color quantification examples in various fields of applications. The objectivity of color-based diagnosis, judgment and control can be significantly improved by the image-based quantification of color proposed in this study.

Color fading naturally occurs with time under light illumination. It is triggered by the high photon energy of light. The rate of color fading and darkening depends on the substance, lighting condition, and storage conditions. Color fading is only observed after some time has passed. The current color of objects of interest can only be compared with old photographs or the observer’s perception at the time of reference. Color fading and color darkening rates between two or more points in time in the past can only be determined using photographic images from the past. For objective characterization of color difference between two or more different times, quantification of color in either digital or printed photographs is required. A newly developed image analysis and comparison software (PicMan) has been used for color quantification and pixel-by-pixel color difference mapping in this study. Images of two copies of Japanese wood-block prints with and without color fading have been selected for the exemplary study of quantitative characterization of color fading and color darkening. The fading occurred during a long period of exposure to light. Pixel-by-pixel, line-by-line, and area-by-area comparisons of color fading and darkening between two images were very effective in quantifying color change and visualization of the phenomena. RGB, HSV, CIE L*a*b* values between images and their differences of a single pixel to areas of interest in any shape can be quantified. Color fading and darkening analysis results were presented in numerical, graphical, and image formats for completeness. All formats have their own advantages and disadvantages over the other formats in terms of data size, complexity, readability, and communication among parties of interest. This paper demonstrates various display options for color analysis, a summary of color fading, or color difference among images of interest for practical artistic, cultural heritage conservation, and museum applications. Color simulation for various moments in time was proposed and demonstrated by interpolation or extrapolation of color change between images, with and without color fading, using PicMan. The degree of color fading and color darkening over the various moments in time (past and future) can be simulated and visualized for decision-making in public display, storage, and restoration planning.

For advanced application specific devices, combinations of Si/Ge, Ge/Si, Si1-xGex/Si are frequently introduced in the device fabrication process. Epitaxy, condensation and annealing processes are commonly used for controlling the Ge content to a desired level. Strain and crystallinity can be affected by a small variation in composition or Ge content, which can result in device performance deterioration or failure. Thus, the composition, strain and crystallinity must be carefully monitored and controlled throughout the manufacturing process. The electrode formation process is also very critical for successful device fabrication. Any spikes and/or electrically active defects near junctions can be fatal to the device yield. Silicidation processes and resulting silicides must be investigated as much as possible using various non-invasive material characterization techniques. In this study, we report the thermal silicidation characteristics of Ni/Si1-xGex with various Ge content under different annealing temperatures in the range of 225oC ~ 400oC in N2 ambient. Thermal silicidation was performed in a stacked hotplate-based SAO-302LP system designed for 300mm wafers. For resulting silicide characterization, measurements of sheet resistance, Raman spectra, X-ray diffraction curves as well as scanning electron microscopy (SEM) observations were performed. We have studied Ge content and annealing temperature dependence on the resulting electrical and crystallographic silicide characteristics. Figure 1 shows 647nm excited Raman spectra and X-ray diffraction (XRD) curves from reference Si, and resulting silicide from Ni/Si0.75Ge0.25 before and after annealing under at 235oC, 310oC and 400oC. Raman spectra and sheet resistance measurements showed silicide formation and silicide layer thickening with increasing annealing temperature. XRD curves clearly indicated the change of crystalline phase of resulting silicide with annealing temperature increase. Various aspects of thermal silicidation and its characterization will be discussed at the conference. Figure 1