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Molecular dynamics simulations are performed in this work at 393 and 323 K for a mesogenic molecule (R)-1-methylheptyl 4[4-(2-allyloxy ethoxy)biphenyl-4¾ -carbonyloxy]benzoate in the simulated smectics A and E, respectively, and in a vacuum at 300 K, for a period of 1.0 ns. The trajectories obtained from molecular dynamics simulations allow us to investigate the dynamical behaviour of this mesogenic molecule in the simulated smectic phases. This dynamical behaviour of a single molecule is presented using the distributions of dihedral angles and rotational diVusion around the C-axis de® ned by the simulated cells. Simulation results indicate that, except for the bonds near the end of the spacer segment, the dihedral angles all exhibit a single Gaussian-like distribution in the smectic A and E phases. Fluctuations of a dihedral angle about its mean value are more restricted in the smectics A and E than in those simulated in a vacuum. The average value of the¯uctuations of the dihedral angles at the bonds in the spacer is found to be about 2 fold larger than that of uctuations in the tail of the same molecule in the smectic A and E phases. In the smectic A phase, the distribution of orientations of a molecule about its long axis in a 36 molecule cell in which the outer molecules are ® xed is found to have three distinct peaks. This result shows that the orientational¯uctuations of single molecules are limited by con® nement due to neighbouring molecules, i.e. that the layers have short-range structural correlations. The orientational distributions show larger¯uctuations at the ends of the molecules.

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Novel ferroelectric liquid crystalline compounds, containing the (S)-2-methyl-1-butyl (4-hydroxybiphenyl-4'-carbonyloxy)biphenyl-4-carboxylate mesogenic group and an oligooxyethylene spacer, were synthesized. The mesomorphic properties of these materials were investigated by differential scanning calorimetry (DSC), optical polarizing microscopy (POM) and powder X-ray diffraction measurement. The results indicate that all members of this series exhibit a very broad temperature mesophase range (reaching a maximum around 210°C) including a blue phase (BP), cholesteric (Ch), twist grain boundary A (TGBA), chiral smectic C (SE), and smectic X (S,) phases. The mesomorphic properties are discussed and a comparison is made with three phenyl rings of ester core analogues.

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