No abstract

This study investigated the determination of Au in rock samples using collision cell quadrupole inductively coupled plasma mass spectrometry (ICP-MS). It is essential to remove various interferents using a collision cell because polyatomic ions such as energy effect (IKEE) due to the potential difference between the plasma and the hexapole affected the reactions in the cell. Au and interfering ions were very sensitive to cell bias voltage (Vc) at constant plasma potential (Vp) and quadrupole bias voltage (Vq). Under the condition of hot plasma, the transmission of ions was promoted, and the maximum Au signal intensity was 50% greater than under normal conditions. At Vc 9 7 V, TaO + ions were removed to background level. Optimized conditions for real sample analysis were obtained by introducing He as an additional collision gas in hot plasma. TaO + ions were removed to background level at He flow rates above 0.6 mL min, and the Au signal remained high. The detection limit (three times the standard deviation of the blank) of this method was 3.06 pg g −1. The results for reference materials (STM-1 and DGPM-1) and spiked samples showed good agreement between specified and measured concentrations.