Nitrous oxide (N 2 0) is a trace gas contributing to stratospheric ozone depletion and global warming. Although a large quantity of information exists about N 2 0 emissions from various ecosystems, this study was initiated to demonstrate the features of N 2 0 emissions from sea-based waste disposal sites in Osaka City in relation to CH 4 emissions.Average N 2 0 emissions at an active landfill (S-Site) were several times higher than those at a closed landfill (N Site). Average CH 4 emissions were also much greater at the S-Site. Regarding the nature of N 2 0 emissions, remarkable emissions often were observed with aerobic waste layers at the N-Site, suggesting almost inversely related N 2 0 emissions with CH 4 production at the N-Site. However, at the S-Site a few exceptionally high N 2 0 emissions were noted in cases of high CH 4 emissions.
Adsorption using activated carbon is one of the most reliable techniques for preventing odor by substances such as H 2 S. Concurrent substances in effluent gas often reduce the removal capacity of activated carbon for H 2 S. As a means of restoring capacity under such conditions, ozone injection into an activated carbon column was examined. When activated carbon was saturated with substances such as toluene, ethanol, n-butanol, or iso-butanol, its capacity to remove H 2 S decreased in proportion to the amount of the saturating substance. Under such conditions, ozone injection greatly increased capacity. Toluene, which is not easily decomposed by ozone, was displaced by ozone and by oxidized products of H 2 S. Ethanol, which is adsorbed in small amounts by activated carbon and easily decomposed by ozone, was removed by ozone injection. Butanols, which are also decomposed by ozone and adsorbed in large quantities by activated carbon, showed intermediate behavior between that of toluene and ethanol.
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