Five-coordinate geometry around ruthenium with highly exposed active sites have attracted intensive scientific interests due to their superior properties and extensive applications. Herein, we report a series of structurally controllable...

A novel binuclear ruthenium-based polyoxometalate, K6H­[{Ru2Cl­(H2O)­(CH3COO)2}­{WO­(H2O)}2(PW9O34)2]·14H2O (1), was successfully synthesized by the conventional hydrothermal method. Compound 1 was well-characterized by single-crystal X-ray diffraction, X-ray powder diffraction (PXRD), infrared (IR) spectroscopy, X-ray photoelectron spectroscopy (XPS), electrospray ionization-mass spectrometry (ESI-MS), thermogravimetric analyses (TGA), and elemental analysis. The structural unit of compound 1 contains two [A-α-PW9O34]9– building blocks at the upper and lower positions connected by two W atoms and two Ru atoms, where the W atoms and Ru atoms are arranged in a trapezoidal arrangement and the Ru atoms are bridged by acetic acid. Furthermore, compound 1 features characteristic absorption bands in the visible region, which allows the investigation of its photocatalytic properties in visible light. Under simulated sunlight radiation (λ > 400 nm), compound 1 exhibits high photocatalytic activity and good circularity toward the oxidative coupling of amines to imines at room temperature with O2 as the sole oxidant.

A novel ruthenium-containing polyoxometalate-based organic-inorganic hybrid, K4Na9H7.4[(AsW9O33)4(WO2)4{Ru3.2(C3H3N2)2}]·42H2O (1) has been successfully synthesized by an one-step hydrothermal method under acidic condition, which applied self-assemble strategy between inorganic polyoxometalate based on trivacant...