The development of light-mediated controlled radical polymerization has benefited from the discovery of novel photocatalysts, which could allow a precise light control over the polymerization process and the production of...

Orthogonal catalysis is emerging as a powerful tool for the synthesis of block copolymers. By employing a single designed dual-function photoredox phosphoric acid catalyst (Photo-PA), the two types of polymerizations...

A class of monophosphonium photocatalysts is developed via the assembly of phosphines and alkynes, and demonstrated as efficient organic photoredox catalysts for the visible light-mediated cationic reversible addition-fragmentation chain transfer...