Four-flux radiative transfer models have been extensively used to describe reflectance and transmittance (R&T) spectra of light scattering and absorbing (S&A) media. Solutions to the differential equations corresponding to the collimated fluxes are obtained by subsequent application of boundary conditions. Explicit expressions for the collimated R&T of light are reported, when considering a light S&A medium contained between two glass slides, an experimental arrangement which is appropriate for liquid suspensions and viscous matrices containing solid particles. A spectral simulated annealing method is applied to retrieve, from measured R&T spectra of collimated light under normal incident radiation, the scattering and absorption coefficients of the composite medium. First, the accuracy of the method is established by applying it to synthetic collimated R&T data. Secondly, we apply the method to experimental data and use it to determine the S&A coefficients of a layer of TiO 2 particles dispersed in a PVP/water matrix.

The high-performance bi-functional electrochromic supercapacitor constitutes the critical technology for intelligent energy conversion and storage. Facilitating ion/electron transport and intercalation/deintercalation by rational design of the highly porous structure with a...

Inorganic electrochromic materials are promising for applications in color-based chromogenic technologies. Limited color control in these materials has, however, hitherto hampered their applications. Here, we show that multicolored nickel oxide (NiO) films can be obtained due to the combined effect of the intrinsic color of NiO and the structural color of the inverse opal structures by tailoring anodic oxide NiO films, exhibiting an absorption tail in the visible region into three-dimensional ordered macroporous inverse opal photonic bandgap structures. Various colors were achieved by the synergistic mechanism of structural and electrochromic coloration, thus realizing a wide spectrum of blue, green, yellow, orange, and brown colors depending on pore size, wall thickness, and viewing angle. Importantly, it is shown that the depth of color can be varied by applying an external potential. The electrochromic coloring of the inverse opal NiO films is found to be very different from the typical optical switching of non-structural NiO films. Thus, our work brings insights into the development of inorganic colored electrochromic materials.

Solutions of the differential equations for the diffuse components of the four-flux model are obtained, including explicit expressions for the collimated-diffuse and diffuse-diffuse reflectance and transmittance for an optical three-layer system. We establish a method to invert collimated-diffuse reflectance and transmittance in order to obtain the spectral variation of all average pathlength parameters and forward scattering ratios, by applying a spectral simulated annealing method. The inversion procedure was tested with synthetic collimated-diffuse reflectance and transmittance spectra and showed very good convergence. Subsequently, the method was applied to measured spectra of a light scattering and absorbing medium containing TiO 2 particles in a lowabsorbing matrix, which was enclosed between two glass slides. Hence the present paper, together with our previous one, wherein we inverted collimated-collimated reflectance and transmittance spectra to obtain scattering and absorption coefficients, establishes a reliable inversion method for obtaining all parameters in the most general version of the four-flux theory from experimental data.