A highly stretchable metal electrode is developed via the solution-processing of very long (>100 μm) metallic nanowires and subsequent percolation network formation via low-temperature nanowelding. The stretchable metal electrode from very long metal nanowires demonstrated high electrical conductivity (~9 ohm sq(-1) ) and mechanical compliance (strain > 460%) at the same time. This method is expected to overcome the performance limitation of the current stretchable electronics such as graphene, carbon nanotubes, and buckled nanoribbons.
In this paper, in order to increase the power conversion efficiency we demonstrated the selective growth of "nanoforest" composed of high density, long branched "treelike" multigeneration hierarchical ZnO nanowire photoanodes. The overall light-conversion efficiency of the branched ZnO nanowire DSSCs was almost 5 times higher than the efficiency of DSSCs constructed by upstanding ZnO nanowires. The efficiency increase is due to greatly enhanced surface area for higher dye loading and light harvesting, and also due to reduced charge recombination by providing direct conduction pathways along the crystalline ZnO "nanotree" multi generation branches. We performed a parametric study to determine optimum hierarchical ZnO nanowire photoanodes through the combination of both length-wise growth and branched growth processes. The novel selective hierarchical growth approach represents a low cost, all solution processed hydrothermal method that yields complex hierarchical ZnO nanowire photoanodes by utilizing a simple engineering of seed particles and capping polymer.
A highly stretchable and transparent electrical heater is demonstrated by constructing a partially embedded silver nanowire percolative network on an elastic substrate. The stretchable network heater is applied on human wrists under real-time strain, bending, and twisting, and has potential for lightweight, biocompatible, and versatile wearable applications.
A facile fast laser nanoscale welding process uses the plasmonic effect at a nanowire (NW) junction to suppress oxidation and successfully fabricate a Cu-NW-based percolation-network conductor. The "nanowelding" process does not require an inert or vacuum environment. Due to the low-temperature and fast-process nature, plasmonic laser nanowelding may form Cu-nanowire networks on heat-sensitive, flexible or even stretchable substrates.
We introduce a facile approach to fabricate a metallic grid transparent conductor on a flexible substrate using selective laser sintering of metal nanoparticle ink. The metallic grid transparent conductors with high transmittance (>85%) and low sheet resistance (30 Ω/sq) are readily produced on glass and polymer substrates at large scale without any vacuum or high-temperature environment. Being a maskless direct writing method, the shape and the parameters of the grid can be easily changed by CAD data. The resultant metallic grid also showed a superior stability in terms of adhesion and bending. This transparent conductor is further applied to the touch screen panel, and it is confirmed that the final device operates firmly under continuous mechanical stress.
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