ABSTRACT. We present studies of 9 modern (up to 400-yr-old) peat sections from Slovenia, Switzerland, Austria, Italy, and Finland. Precise radiocarbon dating of modern samples is possible due to the large bomb peak of atmospheric 14 C concentration in 1963 and the following rapid decline in the 14 C level. All the analyzed 14 C profiles appeared concordant with the shape of the bomb peak of atmospheric 14 C concentration, integrated over some time interval with a length specific to the peat section. In the peat layers covered by the bomb peak, calendar ages of individual peat samples could be determined almost immediately, with an accuracy of 2-3 yr. In the pre-bomb sections, the calendar ages of individual dated samples are determined in the form of multi-modal probability distributions of about 300 yr wide (about AD 1650(about AD -1950. However, simultaneous use of the post-bomb and pre-bomb 14 C dates, and lithological information, enabled the rejection of most modes of probability distributions in the pre-bomb section. In effect, precise age-depth models of the post-bomb sections have been extended back in time, into the "wiggly" part of the 14 C calibration curve.Our study has demonstrated that where annual resolution is concerned, tissues of Sphagnum are the only representative material for 14 C dating, although even samples of pure Sphagnum collected from a very thin slice of the peat section contain tissues grown in different years, so they integrate the atmospheric 14 C signal over a period of time. This time period (0.5-8 yr, depending on the site) seems to correlate with the peat accumulation rate, but it also depends on how the sampled peat sections were handled. When constructing age-depth models, for some peat sections we used the strategy of multi-stage 14 C dating. This led to a drastic reduction in the uncertainty of the age-depth models, by dating only a few additional samples in the profile.Our study is the first in which peat sections from the late pre-bomb time (AD 1900(AD -1960 have been precisely dated at a high temporal resolution. In this time interval, 14 C ages of all the samples dated were younger than those derived from the atmospheric calibration curve, apparently due to the effect of integration. Evidently, the determination of calendar ages based on 14 C dating of single peat samples from that interval may be affected by a serious error if the possibility of integration is ignored.
The concentration of radiocarbon, 14C, in the atmosphere depends on its production rate by cosmic rays, and on the intensity of carbon exchange between the atmosphere and other reservoirs, for example the deep oceans. For the Holocene (the past approximately 11,500 years), it has been shown that fluctuations in atmospheric radiocarbon concentrations have been caused mostly by variations in the solar magnetic field. Recent progress in extending the radiocarbon record backwards in time has indicated especially high atmospheric radiocarbon concentrations in the Younger Dryas cold period, between 12,700 and 11,500 years before the present. These high concentrations have been interpreted as a result of a reduced exchange with the deep-ocean reservoir, caused by a drastic weakening of the deep-ocean ventilation. Here we present a high-resolution reconstruction of atmospheric radiocarbon concentrations, derived from annually laminated sediments of two Polish lakes, Lake Gosciaz and Lake Perespilno. These records indicate that the maximum in atmospheric radiocarbon concentrations in the early Younger Dryas was smaller than previously believed, and might have been caused by variations in solar activity. If so, there is no indication that the deep-ocean ventilation in the Younger Dryas was significantly different from today's.
ABSTRACT. Seven radiocarbon laboratories: Åbo/Aarhus, CIRCE, CIRCe, ETHZ, Poznań, RICH, and Milano-Bicocca performed separation of carbonaceous fractions suitable for
ABSTRACT.A line for preparation of graphite targets for accelerator mass spectrometry (AMS) radiocarbon dating has been built in the Gliwice 14 C Laboratory. The AMS 14 C measurements of our targets are performed in the Leibniz-Labor für Altersbestimmung, Kiel, Germany. The quality of our line has been tested in two series of AMS 14 C measurements of background and Ox-II standard samples and by measurements of the amount of CO 2 released during combustion of sample-free quartz tubes. Most background contamination in the first series was introduced during combustion, which has been greatly reduced by baking quartz tubes vacuum-sealed with CuO and Ag. The residual contamination (ca. 1.5 µg C) seems to come mostly from the quartz tubes themselves. At present, most of the contamination of the background is introduced during graphitization. The reproducibility of background preparations is satisfactory, especially for samples larger than 1.5 mg, when it is better than ± 0.09 pMC. Despite still significant contamination with low-14 C carbon during the graphitization process (corresponding to 1.2 ± 0.2% of 14 C-free carbon), the good reproducibility of the results allows us to use our line in routine 14 C dating.
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