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A B S T R A C TThe present work is concerned with a comparative study to evaluate the adsorptive properties of activated carbons produced from coffee grounds. Activation was done using different chemical activation agents such as H 3 PO 4 and ZnCl 2 either separately or mixed together. Characterization of these prepared samples was carried out by determining their physicochemical properties such as specific surface area, porosity, and surface acidity. The results indicated that the produced carbonaceous materials generally developed different and interesting porous structures. Indeed, H 3 PO 4 -activated carbon (PPAC-P) develops a porous volume of 0.98 cm 3 /g and a surface acidity of 317.6 meq/100 g (with a high mesoporous proportion). By contrast, ZnCl 2 -activated carbon (PPAC-Z) seems to be the most microporous material with a rather limited surface acidity. Adsorption trials with Malathion, a commercial pesticide widely used in Algeria, were carried out onto produced samples of carbonaceous materials in batch experiments at 30˚C. Various parameters such as pH, contact time, nature, and amount of adsorbent were investigated for removal efficiency under different operational conditions. Results herein showed that an interesting removal efficiency of 96% was achieved under the following conditions: pH 6, adsorbent amount of 1 g/L, and an equilibrium time of 60 min.

Problem statement: Debris from construction or demolition/deconstruction processes have no significant impact on the environment as they are res-usable and inert. This has been also long admitted for solid waste generated by the demolition of damaged cities following violent earthquakes. Approach: This study is a contribution to the assessment of actual impact on the quality of groundwater of buried demolition debris from the city of Boumerdes, in the North of Algeria 5 years after the May 21st 2003 earthquake hit the region. The public discharge of Boumerdes city has been used as a temporary landfill. It is located about 5 km downtown of Boumerdes at the Tidjelabine site which is marly-calcareous formation. Leachate from the landfill was directly rejected in the receiving environment, where the soil is marly-calcareous type with cracks giving a variable permeability (10 −2 m sec −1 to nearly 10 −6 m sec) that facilitates infiltration of potential pollutants to the groundwater. The slope character (from 5-10%) of the field contributes to pollutants movement and may accentuate water quality deterioration. Three domestic wells (designated S1, S2 and S3) were selected in the vicinity of the landfill and served as piezometers. Leachate samples were taken from the landfill and evaluated. Results: Leachate analysis indicated organic matter with relatively high COD (1136 mg L . More than five years after the creation of this landfill and despite its predominant C&D nature, these results showed that it was following a typical urban wastes decomposition scheme. Same analysis carried on water samples drawn from the piezometers yielded following results: acidic pH (6.88), acceptable values of target heavy metals concentrations except for Zn with 0.779 mg L −1. Additionally bacteriological cross analysis (membrane filter and multi-tube methods) showed groundwater contamination by total coliforms (1100/100 mL), fecal coliforms (11/100 mL) and fecal streptococci (1100/100 mL). Conclusion: These results proved that leachate had reached the first aquifer horizon about 10 m beneath soil surface. Prior to any remediation program, Management of Boumerdes Municipality is called to quickly implement a reuse and recycling program of the demolition debris in order to stop water reservoirs contamination source.

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