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A novel, ester-free initiator for surface-initiated free radical polymerization has been synthesized and tested. The structurally non-symmetrical azo-based initiator features a chemically stable alkane linker between the initiating group and the silane anchoring group, setting it apart from the majority of surface initiators that are linked by hydrolyzable moieties, such as esters. The novel design of the initiator is bolstered by an original synthetic approach, leading to a greater yield and a dramatic reduction in cyanide usage relative to previous methods. Here we demonstrate the capability of this novel initiator for surface-initiated free radical polymerization (SI-FRP), reverse ATRP, and RAFT, noting that Arrhenius behavior of SI-FRP differs significantly from that of FRP in the bulk. Furthermore, we show that polymer brushes formed from the novel initiator are more stable than those formed from ester-based initiators.

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We report a novel gas-driven high-speed rotating disk electrode (HSRDE). The HSRDE when immersed in an aqueous solution rotates at approximately 650 Hz, generating laminar flow resulting in a diffusion layer, under steady-state conditions, of thickness approximately 2 microm. The use of high-pressure gas to drive the rotator offers significant improvement in electrical noise as compared to conventional mechanically driven devices. The electroanalytical utility of the HSRDE was exemplified by the anodic stripping voltammetry of arsenic(III) at a gold working electrode. The charge under the arsenic stripping peak was found to increase by more than 1 order of magnitude under the enhanced mass transport regime at the HSRDE in comparison to that seen under quiescent conditions.