We report a controllable strain gauge factor obtained using a two-dimensional nanoparticle layer formed from platinum nanoparticles. A vacuum technique is used for room temperature nanoparticle deposition that allows control of the electrical resistance of the film, exhibiting semiconducting-like behavior when nanoparticle arrays cover the surface below a threshold value while above it a metallic behavior is prevalent. The highest sensitivity is obtained for intermediate density values of the nanoparticle assemblies, which could be explained using a tunneling and hopping current expression. The device, which exhibits more than one order of magnitude higher strain sensitivity than continuous metallic films, is fabricated at room temperature through standard lithographic processing allowing for miniaturization and easy integration in silicon technology or flexible substrates.
Ultra-thin alumina films with self-ordered cylindrical vertical pores were fabricated
on a p-type silicon substrate by anodization of Al films with thickness in the
range of 30–500 nm in sulfuric or oxalic acid aqueous solutions. In both cases
the pores were arranged in hexagonal cells in a close-packed structure and their
diameter and density depended on the electrochemical solution used. In the case of
sulfuric acid both 30 and 500 nm Al films resulted in a similar uniform porous
structure using exactly the same anodization conditions for both thicknesses, the
pore diameter being in the range of 10–30 nm and their density of the order of
6–8 × 1010 pores cm−2. In the case of oxalic acid the 500 nm thick films resulted in a uniform porous structure
with larger pores than in sulfuric acid, of diameter in the range of 20–40 nm and a density
of the order of . On the other hand, with oxalic acid it was impossible to form a uniform porous structure
from the 30 nm thick Al film at the same conditions as used for the 500 nm thick
film. Plan-view and cross-sectional transmission electron microscopy was used to
investigate systematically the structure and morphology of the alumina films.
Cross-sectional TEM images showed that the alumina/Si interface was sharp,
but a void was observed beneath each pore, separated from the pore by a thin
alumina layer. The same structure was obtained with both electrolytes. The effect of
pre-annealing of the Al films on the anodic alumina layers was also investigated in
detail.
Direct and high spatial resolution printing of polymer/carbon nanotube (CNT) composite layers has been demonstrated by means of laser induced forward transfer (LIFT). Laser irradiation of composite target materials, such as poly(acrylic acid)/CNT and polyvinylpyrrolidone/CNT, enabled dry deposition of well resolved composite pixels onto glass substrates. The dispersion of the CNT into the deposited composite pixels was investigated by transmission electron microscopy. The LIFT technique was also employed for the accurate deposition of polymer/CNT composite pixels onto aluminum microelectrodes for the fabrication of chemical sensors based on polymer/CNT compounds.
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