For the first time, we report the possibility of utilizing Li2CoPO4F as a novel cathode material for hybrid capacitor applications. Li2CoPO4F powders were prepared by a conventional two-step solid state method. A hybrid cell was fabricated using Li2CoPO4F as the cathode along with activated carbon (AC) as the anode in 1 M LiPF6 dissolved in 1 : 1 EC/DMC electrolyte and its electrochemical properties were examined by cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS) and constant current charge-discharge (C-D) techniques. The Li2CoPO4F/AC cell is capable of delivering a discharge capacitance of 42 F g(-1) at 150 mA g(-1) current density within 0-3 V region having excellent coulombic efficiency of over 99% even after 1000 cycles. Furthermore, the Li2CoPO4F/AC cell exhibited excellent rate performance with an energy density of ~24 W h kg(-1) at 1100 mA g(-1) current and maintained about 92% of its initial value even after 30,000 C-D cycles. Electrochemical impedance spectroscopy was conducted to corroborate the results that were obtained and described.

The high voltage cathode material, Li2CoPO4F was successfully synthesized and coated with various amounts of Al2O3 for enhanced electrochemical performance.

In general, conventional high-T c superconducting fault current limiters (SFCLs) are operated by cooling systems with a liquid cryogen, such as liquid nitrogen (LN2). However, in the fault mode, LN2 evaporates because of joule heating in the SFCL module, so the SFCL system experiences an enormous increase in nitrogen gas volume. In this case, the thermal stability and protection of the system become the primary concerns for the design of the SFCL cooling system. In order to enhance the thermal stability and safety of the system, an SFCL cooled by solid nitrogen (SN2) as a large heat capacitor has been proposed as an alternative. In this paper we report the quench/recovery characteristics of a YBCO-coated conductor (CC) evaluated in an SN2 cooling system for the SFCL. A feasibility study is also conducted on the reference design codes and thermal requirements for the optimal design of the SN2 cooling system. The results demonstrate that the improved thermal contact obtained between the SN2 cooling system and the SFCL module renders the proposed system a suitable cryogen for the SFCL module. Detailed experimental results for the LN2 and SN2 cooling systems are presented and discussed.