c6&70 containing soot was produced by arc-vaporization of graphite. The chromatographic separation of soot yielded fairly pure Cm and C70 samples. High-resolution FT-Raman spectra of c 6 0 and C70 specimen as well as c 6 0 and C70 solutions including polarization measurements are recorded. Compared to the spectrum of solid c60, some Raman bands of the Cm solution change their position and shape. Even the purest commercial C~O samples contain solvent inclusions (impurities) in the order of some percentage. The chromatographic separation combined with Raman polarization measurements of solutions allows an evaluation of the fundamental vibrations of the c 6 0 molecule. Its assignment, in accordance with the group theoretical expectation, is proposed. The existence of small amounts of c 6 0 isomers (symmetry, e.g., Czvr D z~, D z~) in icosahedral c 6 0 (Zh) is affirmed based on the polarization measurements. For C70 the most extended set of Raman frequencies is presented.