K. O. Mineeva scite author profile

The relative monomer reactivities in the reversible addition-fragmentation chain transfer (RAFT) radical copolymerization of styrene (S) and acrylic acid (AA) in a solution of the polar solvent N,Ndimethylformamide are found to be dependent on the chemical nature of the RAFT agent. Polymeric RAFT agents based on polyacrylic acid enhance the difference in monomer reactivities (dithiobenzoate -The opposite effect on the relative reactivity of acrylic acid is observed when polymeric RAFT agents based on polystyrene are usedIn all the investigated systems the copolymers formed are characterized by narrow MWD due to the high efficiency of the chosen RAFT agents.

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K. O. Mineeva

Pseudoliving polymerization of vinyl acetate mediated by reversible addition-fragmentation chain-transfer agents

Homophase and heterophase polymerizations of butyl acrylate mediated by poly(acrylic acid) as a reversible addition–fragmentation chain-transfer agent

Control over the relative reactivities of monomers in RAFT copolymerization of styrene and acrylic acid

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