AISI 304L austenitic stainless steel was modified by using the plasma-based low-energy nitrogen ion implantation (PBLEII) at a process temperature of 400 o C for a processing time of 4 h in order to improve the corrosion-fatigue resistance of the austenitic stainless steel. A single high-nitrogen face-centered-cubic phase ( N) layer with a maximal nitrogen concentration of about 25 at.% was formed on the nitrogen-modified austenitic stainless steel. Compared with the original austenitic stainless steel, the γ N phase layer on the austenitic stainless steel possessed a significant improvement in corrosion resistance in the borate buffer solution with a pH value of 8.4. The corrosion-fatigue properties of the N phase layer on the austenitic stainless steel were examined by the push-pull fatigue experiments with a ratio R of tensile and compression of-1 in the borate buffer solution. The N phase layer has an increased corrosion-fatigue strength up to 230 MPa from 180 MPa of the original austenitic stainless steel with an apparent increase of about 28%. The corrosion-fatigue crack initiation in the N phase layer was found as a controllable stage in the fracture process at the interface between the N phase layer and the austenitic stainless steel matrix with the arc corrosion-fatigue source. Some tiny corrosion-fatigue striations were obtained on the corrosion-fracture surfaces of the N phase layer. The high density of slip bands and dislocations in the N phase layer was able to prevent the crack initiation and propagation, leading to improvement of the corrosion-fatigue properties in the borate buffer solution.
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