Paper is a material known to everybody. It has a network structure consisting of wood fibres that can be mimicked by cooking a portion of spaghetti and pouring it on a plate, to form a planar assembly of fibres that lie roughly horizontal. Real paper also contains other constituents added for technical purposes.This review has two main lines of thought. First, in the introductory part, we consider the physics that one encounters when 'using' paper, an everyday material that exhibits the presence of disorder. Questions arise, for instance, as to why some papers are opaque and others translucent, some are sturdy and others sloppy, some readily absorb drops of liquid while others resist the penetration of water. The mechanical and rheological properties of paper and paperboard are also interesting. They are inherently dependent on moisture content. In humid conditions paper is ductile and soft, in dry conditions brittle and hard.In the second part we explain in more detail research problems concerned with paper. We start with paper structure. Paper is made by dewatering a suspension of fibres starting from very low content of solids. The processes of aggregation, sedimentation and clustering are familiar from statistical mechanics. Statistical growth models or packing models can simulate paper formation well and teach a lot about its structure.The second research area that we consider is the elastic and viscoelastic properties and fracture of paper and paperboard. This has traditionally been the strongest area of paper physics. There are many similarities to, but also important differences from, composite materials. Paper has proved to be convenient test material for new theories in statistical fracture mechanics. Polymer physics and memory effects are encountered when studying creep and stress relaxation in paper. Water is a 'softener' of paper. In humid conditions, the creep rate of paper is much higher than in dry conditions.The third among our topics is the interaction of paper with water. The penetration of water into paper is an interesting transport problem because wood fibres are hygroscopic and swell with water intake. The porous fibre network medium changes as the water first penetrates into the pore space between the fibres and then into the fibres. This is an area where relatively little systematic research has been done. Finally, we summarize our thoughts on paper physics.
The transition in random fiber networks from two-dimensional to three-dimensional planar structure driven by increasing coverage (total fiber length per unit area) is studied with a deposition model. At low coverage the network geometry depends on the scale-free product of fiber length and coverage while at high coverage it depends on a scale-free combination of flexibility, width and thickness of the fibers. With increasing coverage the roughness of the free surface decouples from the substrate, faster when fibers are stiffer. In the high coverage region roughness decreases exponentially with increasing fiber flexibility.
Acoustic emission or crackling noise is measured from an experiment on splitting or peeling of paper. The energy of the events follows a power-law, with an exponent β ∼ 1.8 ± 0.2. The event intervals have a wide range, but superposed on scale-free statistics there is a time-scale, related to the typical spatial scale of the microstructure (a bond between two fibers). Since the peeling takes place via steady-state crack propagation, correlations can be studied with ease and shown to exist in the series of acoustic events.
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