All over the world, almost one billion people live in regions where water is scarce. It is also estimated that by 2035, almost 3.5 billion people will be experiencing water scarcity. Hence, there is a need for water based technologies. In separation processes, membrane based technologies have been a popular choice due to its advantages over other techniques. In recent decades, sustained research in the field of membrane technology has seen a remarkable surge in the development of membrane technology, particularly because of reduction of energy footprints and cost. One such development is the inclusion of nanoparticles in thin film composite membranes, commonly referred to as Thin Film Nanocomposite Membranes (TFN). This review covers the development, characteristics, advantages, and applications of TFN technology since its introduction in 2007 by Hoek. After a brief overview on the existing membrane technology, this review discusses TFN membranes. This discussion includes TFN membrane synthesis, characterization, and enhanced properties due to the incorporation of nanoparticles. An attempt is made to summarize the various nanoparticles used for preparing TFNs and the effects they have on membrane performance towards desalination. The improvement in membrane performance is generally observed in properties such as permeability, selectivity, chlorine stability, and antifouling. Subsequently, the application of TFNs in Reverse Osmosis (RO) alongside other desalination alternatives like Multiple Effect Flash evaporator and Multi-Stage Flash distillation is covered.
Unfortunately, the corresponding author's name was misrepresented and published as "Jegatha Nambi Nambi Krishnan".The correct name "Jegatha Nambi Krishnan" is corrected through this correction.Publisher's Note Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Chlorine is a widely used oxidizing agent in desalination to control bacteria that cause biofouling. The lack of chlorine resistance in commercial desalination membranes urged the development of an alternate polymer material. In this study, commercially available copolymer (SES0005, AquafoneTM), resistant to dissolved chlorine in water, has theoretical IEC of 2.08 meq.g-1 is blended with 0.5-15 %(w/w) TiO2 nanoparticles of <25 nm diameter and 45-55 m2.g-1 surface area by using ball milling device. SEM-EDS (Scanning Electron Microscope-Energy Dispersive Spectroscopy) result supports TiO2 content and uniform distribution. The chlorine stability of membranes was evaluated in sodium hypochlorite solution from 100 to 2000 ppm (pH 9). TGA and FT-IR analysis were performed for these membranes. The 1.5 %(w/w) TiO2 nano-enhanced membrane water retention is 23 % which is ∼53 % higher than that of pristine (15 %) membrane. Tensile strength of pristine and 0.5 %(w/w) TiO2 nano-enhanced membrane is 23, and 44 MPa, respectively. TiO2 nanoparticle addition improved dimensional and mechanical properties. This study attempts to correlate the SES polymer-TiO2 interactions with the characterization techniques.
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