Magnon-polaritons
are shown to play a dominant role in the propagation
of terahertz (THz) waves through TmFeO3 orthoferrite, if
the frequencies of the waves are in the vicinity of the quasi-antiferromagnetic
spin resonance mode. Both time-domain THz transmission and emission
spectroscopies reveal clear beatings between two modes with frequencies
slightly above and slightly below this resonance, respectively. Rigorous
modeling of the interaction between the spins of TmFeO3 and the THz light shows that the frequencies correspond to the upper
and lower magnon-polariton branches. Our findings reveal the previously
ignored importance of propagation effects and polaritons in such heavily
debated areas as THz magnonics and THz spectroscopy of electromagnons.
It also shows that future progress in these areas calls for an interdisciplinary
approach at the interface between magnetism and photonics.
In recent years, methods based on photodissociation in the gas phase have become powerful means in the field of chiral analysis. Among them, infrared multiple photon dissociation (IRMPD) spectroscopy is a very attractive one, since it can provide valuable spectral and structural information of chiral complexes in addition to chiral discrimination. Experimentally, the method can be fulfilled by the isolation of target diastereomeric ions in an ion trap followed by the irradiation of a tunable IR laser. Chiral analysis is performed by comparing the difference existing in the spectra of enantiomers. Combined with theoretical calculations, their structures can be further understood on the molecular scale. By now, lots of chiral molecules, including amino acids and peptides, have been studied with the method combined with theoretical calculations. This review summarizes the relative experimental results obtained, and discusses the limitation and prospects of the method.
Contactless time-resolved optical
pump–probe and external
quantum efficiency measurements were performed in epitaxially grown
free-standing wurtzite indium arsenide/indium aluminum arsenide (InAs-InAlAs)
core–shell nanowires on Si (111) substrate from 77 to 293 K.
The first independent investigation of Shockley–Read–Hall,
radiative, and Auger recombination in InAs-based NWs is presented.
Although the Shockley–Read–Hall recombination coefficient
was found to be at least 2 orders of magnitude larger than the average
experimental values of other reported InAs materials, the Auger recombination
coefficient was reported to be 10-fold smaller. The very low Auger
and high radiative rates result in an estimated peak internal quantum
efficiency of the core–shell nanowires as high as 22% at 77 K,
making these nanowires of potential interest for high-efficiency mid-infrared
emitters. A greater than 2-fold enhancement in minority carrier lifetime
was observed from capping nanowires with a thin InAlAs shell due to
the passivation of surface defects.
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