We demonstrated one-step method to fabricate two different sizes of graphene quantum dots (GQDs) through chemical cutting from graphene oxide (GO), which had many advantages in terms of simple process, low cost, and large scale in manufacturing with higher production yield comparing to the reported methods. Several analytical methods were employed to characterize the composition and morphology of the resultants. Bright blue luminescent GQDs were obtained with a produced yield as high as 34.8%. Moreover, how the different sizes affect fluorescence wavelength mechanism was investigated in details.
Brain-machine interfaces typically rely on electrophysiological signals to interpret and transmit neurological information. In biological systems, however, neurotransmitters are chemical-based inter-neuron messengers. This mismatch can potentially lead to incorrect interpretation of transmitted neuron information. Here we report a chemically mediated artificial neuron that can receive and release the neurotransmitter dopamine. The artificial neuron detects dopamine using a carbon-based electrochemical sensor and then processes the sensory signals using a memristor with synaptic plasticity, before stimulating dopamine release through a heat-responsive hydrogel. The system responds to dopamine exocytosis from rat pheochromocytoma cells and also releases dopamine to activate pheochromocytoma cells, forming a chemical communication loop similar to interneurons. To illustrate the potential of the approach, we show that the artificial neuron can trigger the controllable movement of a mouse leg and a robotic hand.Brain-machine interfaces (BMIs) can bridge the gap between humans and machines through the interpretation and transmission of neurological information. This is a critical process in neuron rehabilitation, cyborg construction and ultimately consciousness detection and control. [1][2][3] Current state-of-the-art BMI technologies rely on the translation of electrophysiological signals, 4-6 such as surface (ex-vivo) or intracellular (in-vivo) bioelectrical potentials. [7][8][9] However, in biological neuronnetworks a large portion of intelligent information -including memory and emotion
We reported a simple and effective way of fabricating one-dimensional (1D) graphene oxide nanoscrolls (GONS) from graphene oxide (GO) sheets through shock cooling by liquid nitrogen. The corresponding mechanism of rolling was proposed. One possibility is the formation of ice crystals during the shock cooling process in liquid nitrogen to be the driving force. The other might be due to the uneven stress of the sheets inside or outside ice during the lyophilization. After reducing, graphene nanoscrolls (GNS) exhibited good structural stability, high specific surface area, and high specific capacitance. The capacitance properties were investigated by cyclic voltammetry, galvanostatic charge-discharge, and electrical impedance spectroscopy. A specific capacity of 156 F/g for the GNS at the current density of 1.0 A/g was obtained comparing with the specific capacity of 108 F/g for graphene sheets. Those results indicated that GNS-based rolling structure could be a kind of promising electrode material for supercapacitors and batteries.
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