The
development of catalysts with high efficiency and stability
in acidic electrolytes for oxygen evolution reaction (OER) is critical
to water electrolyzers and renewable energy conversion and has been
eagerly explored in the shape-controlled synthesis of noble metals
such as Ir and Ru. However, the expensive prices of Ir and Ru severely
hamper their wide use in OER. In this work, we show an efficient method
for the one-pot synthesis of Ir0.4Cu0.6 microspheres.
Electrochemical tests showed that the Ir–Cu microspheres as-synthesized
delivered a prominent electrocatalytic activity toward OER in an acidic
electrolyte with low overpotential (255 mV at 10 mA cm–2) and a small Tafel slope of 53.3 mV decade–1.
They were much better than those of commercial Ir/C (331 mV at 10
mA cm–2 and Tafel slope of 100 mV decade–1). Moreover, the Ir0.4Cu0.6 as-synthesized
also exhibited good stability for OER under acidic conditions, that
is, after 30,000 s, the change of its potential was quite small in
the chronopotentiometry test. The high catalytic performance could
originate from the synergistic electronic interaction between iridium
and copper atoms, which could modify the d-band center of iridium.
noble metal nanostructures have abundant active sites and are ideal catalysts for fuel cell reactions. However, it is still a huge challenge to realize the synthesis of precious metal nanosheets (NSs) with a clean surface. Here, we employed a square-wave potential electrodeposition method to synthesize a three-dimensional (3D) nanostructure composed of 2D maple leaf-like Rh NSs without introducing any surfactants and capping agents. The factors affecting the electrochemical growth of Rh nanoparticles (NPs) were carefully checked. Studies found that the balance between the growth and etching played the key role in the formation of a 3D nanostructure composed of 2D maple leaf-like Rh NSs. Due to the unique morphology and clean surface with a (111) facet, they exhibited excellent electrocatalytic activity and stability to the formic acid oxidation reaction. The peak current density of the maple leaf-like Rh NSs was 3.66 mA cm −2 , which was much higher than those of other Rh NPs prepared by electrodeposition. This work could provide a new idea to construct 3D nanocatalysts with a clean surface for fuel cells.
In the field of catalysis, the design and construction of nanomaterials is an efficient way to optimize the catalytic activity of catalysts. This study presents the synthesis of PtCu tripod...
The bimetallic nanoparticles of Pt-group
metals surrounded by high-index
facets have both alloying electronic effects and surface structure
effects and are promising catalysts for fuel cells. In this work,
the electrochemical square wave potential method was used to prepare
Pt–Rh trioctahedral nanocrystals with {441} high-index facets
without introducing any surfactants. The structures of the nanocrystals
were checked carefully and the effects of parameters such as growth/etching
potential, frequency, concentrations of precursors, etc., were also
investigated systematically. The balance between etching and growth
was found to be crucial in the successful synthesis of Pt–Rh
trioctahedral nanocrystals. Due to the unique surface structure as
well as alloy effect, the prepared Pt–Rh trioctahedral nanocrystals
exhibited excellent electrocatalytic activities for methanol and ethanol
oxidation reactions and were 5.3 times and 3.8 times more active than
those of commercial Pt/C catalysts, respectively. In addition, the
Pt–Rh trioctahedral nanocrystals as-synthesized showed stability
much better than that of commercial Pt/C, which was critical for practical
application.
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