The present study
involves the synthesis, characterization, and
catalytic application of ruthenium nanoparticles (Ru NPs) supported
on plastic-derived carbons (PDCs) synthesized from plastic wastes
(soft drink bottles) as an alternative carbon source. PDCs have been
further activated with CO
2
and characterized by various
analytical techniques. The catalytic activity
of Ru@PDC for the reduction of potassium hexacyanoferrate(III), (K
3
[Fe(CN)
6
]), and new fuchsin (NF) dye by NaBH
4
was performed under mild conditions. The PDCs had spherical
morphology with an average size of 0.5 μm, and the Ru NP (5
± 0.2 nm) loading (4.01 wt %) into the PDC provided high catalytic
performance for catalytic reduction of ferrocyanate(III) and NF dye.
This catalyst can be recycled more than six times with only a minor
loss of its catalytic activity. In addition, the stability and reusability
of the Ru@PDC catalyst are also discussed.
Acid-functionalized
mesoporous carbons (AF-MPCs) have been synthesized
and used as adsorbents for removal of an azo dye, Eriochrome Black-T
(EBT), from aqueous solution. To generate acid surface functionalities,
mesoporous carbons (MPCs) were treated with sulfuric acid. Characterization
of the samples was analyzed by XRD, Raman spectra, N2 adsorption–desorption,
FE-TEM, TGA, and FT-IR studies. The adsorption studies were carried
out under various parameters, such as pH, adsorbent dosage, contact
time, initial dye concentration solution temperature, and salt concentration.
The results showed that the EBT adsorption onto samples was affected
by the pH of solution; the maximum EBT ion adsorption took place at
pH 1; and the adsorption uptake was increased with an increase in
the initial dye concentration. Moreover, the mechanism of adsorption
was investigated using kinetic, diffusion, and isotherm models. The
best fit was obtained by the Langmuir model with high correlation
coefficients (R
2 = 0.9463) with a maximum
monolayer adsorption capacity of 117.0 mg·g–1. The adsorbed anionic EBT dye molecules were eluted by ethanol solvent
with the recovery percentage of 98%. Moreover, this study demonstrates
that AF-MPCs can be successfully used as a low-cost adsorbent for
the removal of EBT from aqueous solutions.
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