The basic factors determining the efficiency of the removal of nitrogen and carbon compounds from airport wastewater containing de-icing agents are low temperature and the C/N ratio (carbon to nitrogen ratio). Biofilm reactors (biofilters) create better conditions for nitrification and denitrification than suspended biomass reactors. The scope of the study included determination of the influence of the C/N ratio in the wastewater on nitrification, denitrification and organic compound removal in biofilm reactors depending on the temperature. The experiment was performed in 24 circular laboratory biofilters with LECA (Light Expanded Clay Aggregates) filling. The study was divided into three series differing in organic carbon loading. In each series, carried out at the same hydraulic retention time, biofilters were operated at 25, 8, 4 or 0 °C. The study showed the effective removal of nitrogen compounds across a very wide temperature range. The applied filling and properly selected operating parameters of the reactors resulted in effective simultaneous nitrification and denitrification. The highest efficiency of nitrogen removal at 0 °C (34.57 ± 4.54%) was obtained at the C/N ratio of 0.5 gC/gN. The efficiency of denitrification (the lowest at the temperature of 0 °C) increased as the temperature and C/N ratio increased in the wastewater.
This study reports results of respirometric measurements of activated sludge biodegrading the substrate in wastewater originating from the following brewery plant production departments: malt house, brewhouse, fermentation house and racking house. The process was conducted at two temperatures: 10 and 20°C with activated sludge adapted to brewery wastewaters. The loading of activated sludge reached 0.25 g chemical oxygen demand per gram dry matter per day, which assured complete degradation of organic matter. The physicochemical characteristics of the wastewaters are provided. The study demonstrates a correlation between the site of wastewater generation, the specific character of a unitary technological process and the quality of the wastewater discharged to the sewage system, including biodegradability. Despite significant differences in the quality of the wastewaters, they were characterized by high biodegradability at a temperature of 10 and 20°C and by the C:N:P ratio being beneficial for biological treatment, irrespective of their source of origin.
Large volumes of pavement de-icing and anti-icing fluids, collectively termed de-icing agents, are used at airports to facilitate wintertime safe air travel. After use, most of the them get typically mixed with storm water runoff and may enter soil and waters near the airports. Wastewater resulting from airports’ winter operations is contaminated mainly with nitrogen and carbon compounds. Previous research results have shown that the use of biofilters filled with lightweight aggregates prepared from fly ash from sewage sludge thermal treatment (FASST LWA) could be an effective method for removing nitrogen and organic compounds at low temperatures, i.e., 0–8 °C. For this to be possible, it is necessary to maintain a proper ratio between the amounts of carbon and nitrogen in the treated wastewater, through the simultaneous application of de-icing agents containing urea and carbon compounds. Biofilter technology is part of the concept of sustainable development. Their filling is made of waste materials and one of the pollutants (organic compounds) present in the wastewater is used to remove other pollutants (nitrogen compounds). In this study, technological systems for the treatment of wastewater containing airport runway de-icing agents with biofilters were proposed, which allow for the treated wastewater to be discharged into natural waters, soil, and sewerage network.
RBC effluent needs further treatment because of water-quality standards requiring low nitrogen and phosphorus concentrations. It may be achieved by using reactors with biomass immobilized on the filling's surface as post-denitrification biofilm reactors. Due to the lack of organic matter in treated wastewater, the introduction of external carbon sources becomes necessary. The new attached growth bioreactor--anaerobic rotating disc batch reactor (ARDBR)--was examined as a post-denitrification reactor. The impact of selected volatile fatty acids on nutrient removal efficiency in an ARDBR was studied. The biofilm was developing on totally submerged discs mounted coaxially on a vertical shaft. Acetic, propionic, butyric and caproic acids were applied. Wastewaters were removed from the reactors after 24-h treatment, together with the excess solids. In the ARDBR tank, there was no biomass in the suspended form at the beginning of the treatment process. Acids with a higher number of carbon atoms (butyric and caproic) were the most efficient in denitrification process. The highest phosphorus removal efficiency was noted in the ARDBR with butyric and propionic acids. The lowest unitary consumption of the external source of carbon in denitrification was recorded for acetic acid, whereas the highest one for caproic acid.
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