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Two-dimensional (2D) intrinsic ferrovalley materials provide unprecedented opportunities to investigate valley physics as well as promising device applications due to their exceptional combination of spontaneous spin and valley polarizations. Here,...

Two-dimensional room-temperature Janus ferrovalley semiconductors with large spin, valley and piezoelectric polarizations provide fertile platforms for designing multifunctional nanodevices. However, few studies have been reported to date in such materials....

Recent experimentally observed intrinsic ferromagnetism in two-dimensional (2D) van der Waals crystals has ignited substantial interests due to their great potential in spintronic devices. However, their practical applications are hampered by rather low Curie temperature and small magnetic anisotropic energy. Here, we predict from first-principles calculations that the 2D pristine hexagonal manganese carbide (h-MnC) sheet exhibits robust ferromagnetic and half-metallic features with complete spin polarization, sizable magnetic anisotropic energy, and wide half-metallic gap near the Fermi energy level. Moreover, the h-MnC sheet can retain its structure up to the temperature of 1000 K, indicating a highly thermodynamic stability. The Monte Carlo simulations based on the Heisenberg model with single-ion anisotropy predict a Curie temperature of 233 K in 2D h-MnC crystal. We confirm the robustness of the ferromagnetism and half-metallicity against the external strain from −6% to 10%. Also, a feasible experimental fabrication route is proposed to realize the h-MnC monolayer via heterostructure engineering and exfoliation techniques. Overall, the robustness of the half-metallicity in combination with the high-temperature ferromagnetism render the freestanding h-MnC monolayer and even its energetically favorable h-MnC/MoS2 and h-MnC/MoSe2 heterostructures quite promising materials for developing practical spintronic nanodevices.