No abstract

Filling and nucleation are the mechanisms of modifying cement paste with nanomaterials, as investigated by previous studies, and are difficult to reflect the different effects of nanomaterials, especially on the changes of cement clinker and hydration products in the cement hydration process. In this study, the mechanisms of modifying cement paste with nano-calcium carbonate (NC), nano-graphene oxide (NG), nano-silica (NS), and nano-titanium dioxide (NT) were investigated by determining the mechanical properties of cement paste treated with nanomaterials and analysing the changes in the cement clinker (tricalcium silicate and dicalcium silicate), hydration products (portlandite and ettringite), and microstructure through many micro-test methods. The results indicate that the incorporation of nanomaterials could improve the early strength of cement paste specimens due to more consumption of cement clinker. Meanwhile, different nanomaterials promote the formation of different hydration products at early ages. C–A–S–H gel, flower-like ettringite, and C–S–H seeds are widely distributed in the cement paste with the incorporation of NC, NG, and NS, respectively. NT exhibits insignificant nucleation effect and has inhibitory effect on portlandite precipitation. This study provides key insights into the mechanism of nanomaterials from the perspective of cement hydration, which may promote the further research and application of nanomaterials in the cement and concrete industries.

No abstract

The research on the highly efficient reutilization of mixed recycled aggregates (MRA) produced from construction and demolition waste has attracted significant attention globally. In this study, the feasibility of using 100% MRA in cement-stabilized materials was investigated. The mechanical properties and microstructures of cement-stabilized MRA (CSMRA) materials containing 100% MRA were systematically examined through unconfined compressive strength (UCS) test, indirect tensile strength (ITS) test, drying shrinkage test, X-ray diffraction analysis, mercury intrusion porosimetry, and scanning electron microscopy. Results showed that the UCS and ITS of CSMRA materials were significantly enhanced with the increase of cement content and curing age, and there was almost a linear relationship between the UCS and ITS. The failure behavior of CSMRA materials under load showed three typical stages: compaction stage, elastic stage, and yield stage. The increase of the cement content caused the drying shrinkage deformation of CSMRA to increase sharply when the cement content exceeded 4%. The microstructural analysis indicated that cement had both filling and binding effects on CSMRA materials. The strength growth with cement content and curing age was because of the constant hydration of cement minerals, producing more calcium silicate hydrate binders between aggregates. Moreover, the increasing cement content could reduce the porosity and optimize the pore structure distribution of CSMRA materials. The findings of this study demonstrate that the use of 100% MRA in cement-stabilized materials as a road base is feasible, which will significantly enhance the utilization efficiency of MRA.

Moisture diffusion in cement-based materials significantly impacts its durability. In this study, we analyzed the effect of adding a waterproofing agent and nano-SiO2 (NS) on the water transportation process in mortar using capillary water absorption tests and nuclear magnetic resonance (NMR) technology. The results indicate that the combined action of the waterproofing agent and nano-SiO2 drastically reduce the capillary water absorption coefficient and have a more significant impact than only adding the waterproofing agent. The moisture diffusion in different sections of the mortar during the water absorption process is obtained from the NMR test results and two function models. Comparative studies indicate that the NMR test results have good correlation with the capillary water absorption test results and provide accurate process data. The NMR analysis results offer a new analytical method to characterize the porosity of cement-based materials by continuously monitoring small-pitch sections.