Understanding the end-Triassic mass extinction event (201.36 Ma) requires a clear insight into the stratigraphy of boundary sections, which allows for long-distance correlations and correct distinction of the sequence of events. However, even after the ratification of a Global Stratotype Section and Point, global correlations of TJB successions are hampered by the fact that many of the traditionally used fossil groups were severely affected by the crisis. Here, a new correlation of key TJB successions in Europe, U.S.A. and Peru, based on a combination of biotic (palynology and ammonites), geochemical (δ 13 C org ) and radiometric (U/Pb ages) constraints, is presented. This new correlation has an impact on the causality and temporal development during the end-Triassic event. It challenges the hitherto used standard correlation, which has formed the basis for a hypothesis that the extinction was caused by more or less instantaneous release of large quantities of light carbon (methane) to the atmosphere, with catastrophic global warming as a consequence. The new correlation instead advocates a more prolonged scenario with a series of feedback mechanisms, as it indicates that the bulk of the hitherto dated, high-titanium, quartz normalized volcanism of the Central Atlantic Magmatic Province (CAMP) preceded or was contemporaneous to the onset of the mass extinction. In addition, the maximum phase of the mass extinction, which affected both the terrestrial and marine ecosystems, was associated with a major regression and repeated, enhanced earthquake activity in Europe. A subsequent transgression resulted in the formation of hiati or condensed successions in many areas in Europe. Later phases of volcanic activity of the CAMP, producing low titanium, quartz normalized and high-iron, quartz normalized basaltic rocks, continued close to the first occurrence of Jurassic ammonites and the defined TJB. During this time the terrestrial ecosystem had begun to recover, but the marine ecosystem remained disturbed.
Profound changes in both marine and terrestrial biota during the end-Triassic mass extinction event and associated successive carbon cycle perturbations across the Triassic-Jurassic boundary (T-J, 201.3 Ma) have primarily been attributed to volcanic emissions from the Central Atlantic Magmatic Province and/or injection of methane. Here we present a new extended organic carbon isotope record from a cored T-J boundary succession in the Danish Basin, dated by high-resolution palynostratigraphy and supplemented by a marine faunal record. Correlated with reference C-isotope and biotic records from the UK, it provides new evidence that the major biotic changes, both on land and in the oceans, commenced prior to the most prominent negative C-isotope excursion. If massive methane release was involved, it did not trigger the end-Triassic mass extinction. Instead, this negative C-isotope excursion is contemporaneous with the onset of fl oral recovery on land, whereas marine ecosystems remained perturbed. The decoupling between ecosystem recovery on land and in the sea is more likely explained by long-term fl ood basalt volcanism releasing both SO 2 and CO 2 with short-and long-term effects, respectively.
Absolute abundances (concentrations) of dinoflagellate cysts are often determined through the addition of Lycopodium clavatum marker-grains as a spike to a sample before palynological processing. An interlaboratory calibration exercise was set up in order to test the comparability of results obtained in different laboratories, each using its own preparation method. Each of the 23 laboratories received the same amount of homogenized splits of four Quaternary sediment samples. The samples originate from different localities and consisted of a variety of lithologies. Dinoflagellate cysts were extracted and counted, and relative and absolute abundances were calculated. The relative abundances proved to be fairly reproducible, notwithstanding a need for taxonomic calibration. By contrast, excessive loss of Lycopodium spores during sample preparation resulted in non-reproducibility of absolute abundances. Use of oxidation, KOH, warm acids, acetolysis, mesh sizes larger than 15 µm and long ultrasonication (N 1 min) must be avoided to determine reproducible absolute abundances. The results of this work therefore indicate that the dinoflagellate cyst worker should make a choice between using the proposed standard method which circumvents critical steps, adding Lycopodium tablets at the end of the preparation and using an alternative method.
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