The mechanism of silsesquioxane growth is studied with an insertion mechanism analogous to the one
previously proposed for fullerene growth. Different from previous work, the possibility of the involvement
of larger rings with (SiO)7 size in cages of hydridosilsesquioxanes Si
n
O3
n
/2H
n
is investigated. Such a nonclassical
pathway is calculated for the growth of Si30O45H30 via Si32O48H32 to Si34O51H34. The MSINDO method is
used to determine the transition structures and intermediates. It is found that nonclassical pathways are equally
preferable as classical pathways involving cages with (SiO)5 and (SiO)6 rings only.
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