A liquid droplet dispensed over a sufficiently hot surface does not make contact but instead hovers on a cushion of its own self-generated vapor. Since its discovery in 1756, this so-called Leidenfrost effect has been intensively studied. Here we report a remarkable self-propulsion mechanism of Leidenfrost droplets against gravity, that we term Leidenfrost droplet trampolining. Leidenfrost droplets gently deposited on fully rigid surfaces experience self-induced spontaneous oscillations and start to gradually bounce from an initial resting altitude to increasing heights, thereby violating the traditionally accepted Leidenfrost equilibrium. We found that the continuously draining vapor cushion initiates and fuels Leidenfrost trampolining by inducing ripples on the droplet bottom surface, which translate into pressure oscillations and induce self-sustained periodic vertical droplet bouncing over a broad range of experimental conditions.

Drop-surface interaction is predominant in nature as well as in many industrial applications. Superhydrophobic surfaces show potential for various applications as they show complete drop rebound. In a recent work, it has been reported that the drop lift-off time on a superhydrophobic substrate could be further reduced by introducing a macro-ridge. The macro-ridge introduces asymmetry on the morphology of drop spreading and retraction on the surface. This changes the hydrodynamics of drop retraction and reduces the lift-off time. Keeping practical applications in view, we decorate the surface with multiple ridges. The morphology of the hydrodynamic asymmetry is completely different for the drops impacting onto the tip of the ridges from those impacting onto the middle of the valley between the ridges. We show that the morphology forms the key to the lift-off time. We also show that the outward flow from the ridge triggers a Laplace pressure driven de-wetting on the tip of the ridge, thus aiding the lift-off time. At the end of this work, we propose a ridge to ridge separation that effectively reduces the lift-off times for impacts both at the tip of the ridge and offset from it.

Organic hydrophobic layers targeting sustained dropwise condensation are highly desirable but suffer from poor chemical and mechanical stability, combined with low thermal conductivity. The requirement of such layers to remain ultrathin to minimize their inherent thermal resistance competes against durability considerations. Here, we investigate the long-term durability and enhanced heat-transfer performance of perfluorodecanethiol (PFDT) coatings compared to alternative organic coatings, namely, perfluorodecyltriethoxysilane (PFDTS) and perfluorodecyl acrylate (PFDA), the latter fabricated with initiated chemical vapor deposition (iCVD), in condensation heat transfer and under the challenging operating conditions of intense flow (up to 9 m s –1 ) of superheated steam (111 °C) at high pressures (1.42 bar). We find that the thiol coating clearly outperforms the silane coating in terms of both heat transfer and durability. In addition, despite being only a monolayer, it clearly also outperforms the iCVD-fabricated PFDA coating in terms of durability. Remarkably, the thiol layer exhibited dropwise condensation for at least 63 h (>2× times more than the PFDA coating, which survived for 30 h), without any visible deterioration, showcasing its hydrolytic stability. The cost of thiol functionalization per area was also the lowest as compared to all of the other surface hydrophobic treatments used in this study, thus making it the most efficient option for practical applications on copper substrates.

Rapid shedding of impinging water drops is crucial in a cold habitat for diverse reasons spanning from self-cleaning to thermal regulation in most plants, animals, and industrial applications as well. It was shown recently that deploying linear millimetric ridges on a superhydrophobic surface can reduce the contact time (for drops crashing normally) up to 50% compared to a flat surface. However, the contact time rises for drops impacting at an increasing offset to the structure. Counter-intuitively, we demonstrate a ski-jumping mechanism occurring only over a range of offsets from the macro-structure with a remarkable reduction in contact time (∼65%) during oblique impacts. Theoretically, the reduction can be as high as 80%. The flow hydrodynamics is very similar to the oblique impacts on a flat surface. However, the architecture of ridge allows the drop to rapidly fly away from the surface. This work provides new insight which can be useful for the design of surfaces with high water repellency.

Water drop impacting a superhydrophobic surface (SHS) rebounds completely with remarkable elasticity. For such an impact, the balance between the inertial and capillary forces ascertain the contact time. This is found to be fairly constant for any macroscopically flat SHS and for a given drop volume. Recently, various studies have shown that breaking the radial symmetry during the drop impact can significantly reduce the contact time below that of a flat SHS. One such study has been performed on a cylindrical SHS with a curvature comparable to the drop. The reduction in contact time has been attributed to the radially anisotropic flow imparted by the tangential component of momentum and the elliptical footprint of the drop during the crash. Here, we perform drop impact experiments on bathtub-like SHS and show that the radial anisotropy can be triggered even in the absence of both the criteria mentioned above. This is shown to be a consequence of the lamella deflection during the spreading of the drop. The reduction in contact time is quite clearly evident in this experimental regime.