Industrial and urban dusts were characterized by investigating their magnetic properties. Topsoil composed of technogenic magnetic particles (TMP) originating from areas affected by three ironworks, street dust mainly composed of traffic-related pollution, and particulate matter (PM) from urban agglomeration in Warsaw, Poland were investigated. Several magnetic methods, namely magnetic susceptibility, thermomagnetic curves, hysteresis loops, decomposition of isothermal remanent magnetization acquisition curves, and first-order reversal curves, were performed to evaluate the magnetic fraction of dust. Magnetite was the main magnetic phase in all types of samples, with a small amount of high-coercive hematite within ironworks and street dust samples. Significant differences were observed in the domain structure (grain size) of industrial and traffic-related magnetic particles. The grain size of TMP obtained from steel production was in the range of 5–20 µm and was predominated by a mixture of single-domain (SD) and multidomain (MD) grains, with the prevalence of SD grains in the topsoil affected by Třinec ironwork. The traffic-related dust contained finer grains with a size of about 0.1 µm, which is characteristic of the pseudo-single-domain (PSD)/SD threshold. Street dusts were composed of a slightly higher proportion of MD grains, while PM also revealed the typical behavior of superparamagnetic particles.
The lockdown in 2020 implemented due to the SARS-CoV-2 pandemic has resulted in a significant improvement in air quality at a global scale. Nationwide lockdown also considerably improved air quality at a local scale, especially in cities which were almost completely shut down during the first coronavirus wave, with nearly no activity. We tested the hypothesis that a reduction in the intensity of vehicle traffic causes a drastic decrease in urban air pollution at a local scale. We focused on two urban agglomerations, Warsaw and Cracow, in Poland. Data of the concentrations of traffic-related sources, namely NOx, PM10, and PM2.5, obtained from two air pollution monitoring stations were analyzed for the years 2020 and 2021, during which lockdown and pandemic restrictions were in effect, and for 2019, as a reference. In the years 2020–2021, the average annual concentration of NOx was decreased by ~ 19%, PM2.5 by ~ 19%, and PM10 by ~ 18% in Warsaw, while in Cracow the average annual concentration of NOx was decreased by ~ 16%, PM2.5 by ~ 22%, and PM10 by ~ 2%, compared to 2019. The contribution from traffic-related sources to the overall level of air pollution was estimated. The results indicated that ~ 30 µg/m3 of PM10, ~ 15 µg/m3 of PM2.5, and ~ 120 µg/m3 of NOx in Cracow, and ~ 20 µg/m3 of PM2.5 in Warsaw originate from moving vehicles. The nationwide lockdown allowed us to conduct this study to understand how a reduction in local traffic emissions can decrease ambient air pollution levels.
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