The applicability of more than 70 semi‐crystalline polymer grades with different melting temperatures as phase change materials (PCM) is investigated. Their storage capacity (heat of fusion) and application temperature range (defined by the melting temperature range and the degradation behavior) are analyzed via differential scanning calorimetry (DSC). Application‐oriented stability investigations (thermal cycling and exposure to static thermal load above the polymer’s melting temperature) are applied on the most promising polymer types. The thermal and thermo‐oxidative degradation behavior is monitored via DSC and Fourier‐transform infrared spectroscopy. Different aging phenomena are identified. However, these have only little impact on the polymer’s storage capacity. Therefore, a great potential of polymers as PCM is revealed. Additionally, the economic efficiency of polymers as PCM is estimated and discussed.
Micro- and nanoplastics (MNPs) are recognized as emerging contaminants, especially in food, with unknown health significance. MNPs passing through the gastrointestinal tract have been brought in context with disruption of the gut microbiome. Several molecular mechanisms have been described to facilitate tissue uptake of MNPs, which then are involved in local inflammatory and immune responses. Furthermore, MNPs can act as potential transporters (“vectors”) of contaminants and as chemosensitizers for toxic substances (“Trojan Horse effect”). In this review, we summarize current multidisciplinary knowledge of ingested MNPs and their potential adverse health effects. We discuss new insights into analytical and molecular modeling tools to help us better understand the local deposition and uptake of MNPs that might drive carcinogenic signaling. We present bioethical insights to basically re-consider the “culture of consumerism.” Finally, we map out prominent research questions in accordance with the Sustainable Development Goals of the United Nations.
This paper describes the development of a novel thermoset based on epoxidized hemp seed oil. The optimization of the hardener (anhydride) and crosslinking accelerator (2‐ethylimidazol) concentration as well as the curing parameters are discussed in detail. The optimized material exhibits a bio‐based carbon portion of 57.5 wt% and represents an innovative and sustainable substitute for fully petrochemical‐based resins in terms of thermal and mechanical performance characteristics. However, also a major challenge with regard to practical applications of (bio‐based) thermosets with anhydride curing agent thermosets is identified and addressed: the sensitivity to moisture absorption both during curing and in the fully cured state.
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