Samples of pure ferric oxide gel have been calcined for 5 hours a t a succession of fixed temperatures T, between 50" and 800°, and the following properties of the product measured on cooling: (a) sorption of nitrogen and of oxygen a t -183";(b) sorption of carbon tetrachloride a t 25"; (c) heat of immersion in carbon tetrachloride and in decalin; (d) apparent density in various liquids ; ( e ) dissolution when immersed alternately in sodium dithionite (hyposulphite) and in hydrochloric acid ; (f) rate of dissolution in hydrochloric acid; (g) X-ray powder photographs. The specific surface area S obtained from (u), ( b ) , and (c) fell continuously from the lowest temperature investigated, so that-contrary to, e.g., the production of magnesia from magnesium hydroxide-there is no maximum in the curve of S against temperature of calcination. This is probably because ferric oxide gel on being heated does not undergo a polymorphic change but merely loses its water continuously from an amorphous or slightly organised condition.The data for apparent density reveal the presence of pores of micro-and molecular dimensions for all values of T , up to 800". The rate Y of dissolution per unit area varies but little with T, in the presence of the reducing agent; whereas in the absence of the reducing agent, the rate Y , which likewise varies little with T, from 150" to 500", drops markedly for the 800" sample, probably because the lattice first becomes destrained in this sample.
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