Carbon dots (CDs) synthesized from biological sources have attracted much interest in bioimaging and biomedical applications due to their excellent biocompatibility, and thus, a facile synthesis of CDs with high fluorescence quantum yield (QY) is requisite for practical applications. In this work, we report a simple, rapid, and green approach to synthesize photoluminescent CDs using eutrophic algal blooms as the carbon source. This method offers a possibility for large scale production of highly luminescent CDs (QY = 13%) with the average particle size ∼8 nm. These CDs are highly water-soluble and exhibit nanosecond fluorescence lifetime with high photostability, luminescence stability in different environments, low cytotoxicity, and excellent cell permeability. Laser scanning confocal microscopy shows the uptake of CDs by MCF-7 cells, and the destined application of these CDs as a potential biomarker is demonstrated.
Synthesis of highly
luminescent carbon dots (CDs) from waste materials
gains much attention in the current scenario. We have converted waste
expanded polystyrene (EPS), a nonbiodegradable environmental pollutant,
into multifunctionalized fluorescent CDs. This can be a good scaling
up approach for the large-scale synthesis of nitrogen-doped CDs with
a high photoluminescence (PL) quantum yield (QY) of ∼20%. The
as prepared CDs exhibit excellent water solubility and a longer PL
lifetime (in nanoseconds). They also possess excellent photostability,
low cytotoxicity, and stable luminescence QY in different solution
environments. Selective and sensitive detection of Au3+ ions is demonstrated using these CDs as fluorescence probes, and
a LOD of 53 nM is achieved. A detailed investigation revealed that
the observed PL quenching is due to “coordination-induced aggregation
caused PL quenching” mechanism.
Synthesizing nano carbon from its bulk precursors is of recent research interest. In this report, luminescent carbon nanoparticles (CNPs) with tunable particle size and surface functionality are fabricated from lignite using ethylenediamine as the reactive solvent and surface passivating agent via different experimental methods. From the steady-state and time-resolved photophysical studies of these differently sized CNPs, it is unveiled that the energy of the excitons generated after photoexcitation is quantum confined, and it influences the observed photophysical behaviour significantly only when the particle size is less than 10 nm. A larger size of the CNPs and less surface functionalization lead to aggregation, and quenching of the fluorescence. But by dispersing smaller size CNPs in sodium sulfate matrix exhibits fluorescence in the solid state with an absolute fluorescence quantum yield of ∼34%. The prospective application of this hybrid material in sensing and removal of moisture in the atmosphere is illustrated.
N-CDs are synthesized by an outright green method and employed as a selective fluorescent probe for Au3+ ions and is also used as a reducing agent to synthesize AuNPs.
Photoluminescent carbon dots (PL CDs) have drawn tremendous attention from researchers owing to their admirable properties and wide range of applications. Herein, highly PL nitrogen and sulfur doped carbon dots (N,S-CDs) were synthesized through a facile, green and rapid one-step microwave assisted method using goat hooves, a bio-waste and a green precursor. The structural and photophysical properties of as obtained N,S-CDs were thoroughly investigated. From the investigation, it is revealed that the N,S-CDs possess a spherical morphology with an average particle size of about 2 nm, highly amorphous nature, high functionality, negative zeta potential (À32 mV), good water-solubility, excitation dependant PL, high PL quantum yield (23.8%), nanosecond lifetime (s avg ¼ 3.38 ns) and excellent storage stability for 180 days without any agglomeration. In addition, the N,S-CDs exhibit high PL stability under diverse pH conditions, wide ionic strength and resistance towards photobleaching, which are very important properties for practical applications. The N,S-CDs selectively sense Au 3+ ions and also reduce the Au 3+ ions to metallic gold. Hence, the N,S-CDs were successfully applied as a potential candidate for sensing of Au 3+ and simultaneous extraction of metallic gold in aqueous media without any further reducing agents. It is a significant green way for the recovery of gold in aqueous media.
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