To understand deep groundwater flow systems and their interaction with CO 2 emanated from magma at depth in a volcanic edifice, deep groundwater samples were collected from hot spring wells in the Aso volcanic area for hydrogen, oxygen and carbon isotope analyses and measurements of the stable carbon isotope ratios and concentrations of dissolved inorganic carbon (DIC). Relations between the stable carbon isotope ratio (δ 13 C DIC ) and DIC concentrations of the sampled waters show that magma-derived CO 2 mixed into the deep groundwater. Furthermore, groundwaters of deeper areas, except samples from fumarolic areas, show higher δ 13 C DIC values. The waters' stable hydrogen and oxygen isotope ratios (δD and δ 18 O) reflect the meteoric-water origin of that region's deep groundwater. A negative correlation was found between the altitude of the well bottom and the altitude of groundwater recharge as calculated using the equation of the recharge-water line and δD value. This applies especially in the Aso-dani area, where deeper groundwater correlates with higher recharge. Groundwater recharged at high altitude has higher δ 13 C DIC of than groundwater recharged at low altitude, strongly suggesting that magmatic CO 2 is present to a much greater degree in deeper groundwater. These results indicate that magmatic CO 2 mixes into deeper groundwater flowing nearer the magma conduit or chamber.

The 2008 Iwate-Miyagi Nairiku earthquake (M 7.2) was a shallow inland earthquake that occurred in the volcanic front of the northeastern Japan arc. To understand why the earthquake occurred beneath an active volcanic area, in which ductile crust generally impedes fault rupture, we conducted magnetotelluric surveys at 14 stations around the epicentral area 2 months after the earthquake. Based on 56 sets of magnetotelluric impedances measured by the present and previous surveys, we estimated the three-dimensional (3-D) electrical resistivity distribution. The inverted 3-D resistivity model showed a shallow conductive zone beneath the Kitakami Lowland and a few conductive patches beneath active volcanic areas. The shallow conductive zone is interpreted as Tertiary sedimentary rocks. The deeper conductive patches probably relate to volcanic activities and possibly indicate high-temperature anomalies. Aftershocks were distributed mainly in the resistive zone, interpreted as a brittle zone, and not in these conductive areas, interpreted as ductile zones. The size of the brittle zone seems large enough for a fault rupture area capable of generating an M 7-class earthquake, despite the areas distributed among the ductile zones. This interpretation implies that 3-D elastic heterogeneity, due to regional geology and volcanic activities, controls the size of the fault rupture zone. Additionally, the elastic heterogeneities could result in local stress concentration around the earthquake area and cause faulting.

One feature of volcanic lakes influenced by subaqueous fumaroles existing at lake bottoms (called active crater lakes) is the remarkable color of their waters: turquoise or emerald green. The active crater lake named Yudamari at Mt. Nakadake of Aso volcano, Japan, takes on a milky pale blue-green. The particular blue component of the lake water color results from Rayleigh scattering of sunlight by very fine aqueous colloidal sulfur particles; the green component is attributable to absorption of sunlight by dissolved ferrous ions. An objective color observation conducted during 2000-2007 revealed that the lake water color changed from blue-green to solid green. The disappearance of the blue ingredient of the water color will result in diminution of aqueous colloidal sulfur from chemical analyses of lake waters sampled simultaneously. The aqueous sulfur is produced by the reaction of sulfur dioxide and hydrogen sulfide supplied from subaqueous fumaroles. However, its production efficiency decreases by domination of sulfur dioxide in the subaqueous fumarolic sulfur gas species with increasing subaqueous fumarolic temperature. The disappearance of blue ingredients from the blue-green color of the lake water may be attributed to activation of subaqueous fumarole activity.

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