Nitrogen doping is expected to provide several intriguing properties to graphene. Nitrogen plasma treatment to defect-free and defective highly oriented pyrolytic graphite (HOPG) samples causes doping of nitrogen atom into the graphene layer. Nitrogen atoms are initially doped at a graphitic site (inside the graphene) for the defect-free HOPG, while doping to a pyridinic or a pyrrolic site (edge of the graphene) is dominant for the defective HOPG. The work function of graphene correlates strongly with the site and amount of doped nitrogen. Nitrogen atoms doped at a graphitic site lower the work function, while nitrogen atoms at a pyridinic or a pyrrolic site increase the work function. Control of plasma treatment time and the amount of initial defect could change the work function of graphite from 4.3 eV to 5.4 eV, which would open a way to tailor the nature of graphene for various industrial applications.

We report synchrotron-based operando soft X-ray microscopic photoelectron spectroscopy under charge-discharge control of single crystalline LiCoO 2 (LCO) particles as an active electrode material for an all solid-state lithium-ion battery (LIB). Photoelectron mapping and the photoelectron spectrum of a selected microscopic region are obtained by a customized operando cell for LIBs. During the charge process, a more effective Li extraction from a side facet of the single crystalline LCO particle than from the central part is observed, which ensures the reliability of the system as an operando microscopic photoelectron analyzer that can track changes in the electronic structure of a selected part of the active particle. Based on these assessments, the no drastic change in the Co 2 p XPS spectra during charge-discharge of LCO supports that the charge-polarization may occur at the oxygen side by strong hybridization between Co 3 d and O 2 p orbitals. The success of tracking the electronic-structure change at each facet of a single crystalline electrode material during charge-discharge is a major step toward the fabrication of innovative active electrode materials for LIBs.

Graphite-related materials play an important role in various kinds of devices and catalysts. Controlling the properties of such materials is of great significance to widen the potential applications and improve the performance of such applications as field emission devices and catalyst for fuel cells. In particular, the work function strongly affects the performance, and thus development of methods to tune the work function widely is urgently required. Here, we achieved wide-range control of the work function of graphite by nitrogen and hydrogen plasma treatments. The time of hydrogen plasma treatment and the amount of nitrogen atoms doped beforehand could control the work function of graphite from 2.9 to 5.0 eV. The formation of a surface dipole layer and the nitrogen-derived electron donation contributed to such lowering of the work function, which is advantageous for applications in various fields.

In this study, soft X-ray emission spectroscopy of an aqueous colloidal dispersion of multi-wall carbon nanotubes modified via plasma process in an aqueous solution was performed for investigating the electronic...