The X-Ray Imaging and Spectroscopy Mission (XRISM) is the successor to the 2016 Hitomi mission that ended prematurely. Like Hitomi, the primary science goals are to examine astrophysical problems with precise highresolution X-ray spectroscopy. XRISM promises to discover new horizons in X-ray astronomy. XRISM carries a 6 x 6 pixelized X-ray micro-calorimeter on the focal plane of an X-ray mirror assembly and a co-aligned X-ray CCD camera that covers the same energy band over a large field of view. XRISM utilizes Hitomi heritage, but all designs were reviewed. The attitude and orbit control system were improved in hardware and software. The number of star sensors were increased from two to three to improve coverage and robustness in onboard attitude determination and to obtain a wider field of view sun sensor. The fault detection, isolation, and reconfiguration (FDIR) system was carefully examined and reconfigured. Together with a planned increase of ground support stations, the survivability of the spacecraft is significantly improved.

The acoustic properties of composite materials used for an intermediate layer or backing of an ultrasonic transducer are studied experimentally. (0-3) composite materials are formed from a mixture of epoxy resin and tungsten powder for various weight ratios and their acoustic properties are measured. The experimental results are compared with the results predicted by different models, which are based on the elastic-wave scattering theory, to verify if the measured acoustic properties agree with theoretical estimations. For the ultrasonic velocities, the estimations of the Devaney model were closest to the experimental results. The weight fractions of tungsten powder for the composite materials, which have objective acoustic properties, can easily be estimated by theoretical calculations using the Devaney model.

The potential of a new anionic octahedral metal complex [Ru(III)(acac)2(pz)2](-) ((-)) (pzH = pyrazole) as a ligand with a scorpionate coordination behaviour like tris(pyrazolyl)borate (tp) and reversible redox activity is presented. Trinuclear metal complexes, [Ru(III)2Zn(II)(acac)4(pz)4] () and [Ru(II)Ru(III)2(acac)4(pz)4] (), were each synthesized by the reaction of ZnCl2 or Ru3(CO)12 with [Ru(III)(acac)2(pz)(pzH)] (H) that is in situ deprotonated and acts as a precursor of (-). Single-crystal X-ray diffraction studies clarified that (-) acts as a scorpionate ligand; two (-) units in and one unit in function as bidentate ligands with two pyrazolates as pincers, while another (-) unit in functions as a tridentate ligand with one oxygen atom as a tail in addition to the two pyrazolate pincers. Moreover, and showed reversible multi-stage redox behaviours based on the Ru(II)/Ru(III) and Ru(III)/Ru(IV) couples of the (-) units in the cyclic voltammetry (CV) measurements. Based on the X-ray, IR, and CV measurements and the comparison with other Ru(ii) complexes with tp derivatives, the (-) unit was found to act as a redox-active scorpionate with electron withdrawing properties compared to the tp.

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