Abstract. The Curiosity rover discovered fine--grained sedimentary rocks, inferred to represent an ancient lake, preserve evidence of an environment that would have been suited to support a Martian biosphere founded on chemolithoautotrophy. This aqueous environment was characterized by neutral pH, low salinity, and variable redox states of both iron and sulfur species. C, H, O, S, N, and P were measured directly as key biogenic elements, and by inference N and P are assumed to have been available. The environment likely had a minimum duration of hundreds to tens of thousands of years. These results highlight the biological viability of fluvial--lacustrine environments in the post--Noachian history of Mars.

Abstract. High-precision stepped-heating experiments were performed to better characterize helium diffusion from apatite using Durango fluorapatite as a model system. At temperatures below 265øC, helium diffusion from this apatite is a simple, thermally activated process that is independent of the cumulative fraction of helium released and also of the heating schedule used. Across a factor of -4 in grain size, helium diffusivity scales with the inverse square of grain radius, implying that the physical grain is the diffusion domain. Measurements on crystallographically oriented thick sections indicate that helium diffusivity in Durango apatite is nearly isotropic. The best estimate of the activation energy for He diffusion from this apatite is E a = 33 _+ 0.5 kcal/mol, with log(D0) = 1.5 +_ 0.6 cm2/s. The implied He closure temperature for a grain of 100 •m radius is 68øC assuming a 10øC/Myr cooling rate; this figure varies by _5øC for grains ranging from 50 to 150 •m radius. When this apatite is heated to temperatures from 265 to 400øC, a progressive and irreversible change in He diffusion behavior occurs: Both the activation energy and frequency factor are reduced. This transition in behavior coincides closely with progressive annealing of radiation damage in Durango apatite, suggesting that defects and defect annealing play a role in the diffusivity of helium through apatite. ]. However, important questions remain regarding the behavior of He diffusion from apatite, justifying this detailed laboratory study. A precise and accurate knowledge of the diffusion behavior of a radiogenic daughter product is required to establish the temperature range over which a particular dating technique is sensitive. In the simplest case, the radiogenic daughter product would be lost by volume diffusion involving a single, thermally activated process for all of the daughter in the crystal. Under such conditions the temperature dependence of diffusivity is characterized by an activation energy (E,) and diffusivity at infinite temperature (Do): D/a 2 = Do/a 2 exp(-E,/RT), where R is the gas constant, T is the temperature, and a is the diffusion domain radius. Laboratory measurements of diffusivity over a range of temperatures will in this case yield a line on an Arrhenius plot with slope proportional to E, and y intercept of ln(Do/a2). From these two quantities a closure tem-

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[1] High topography in central Asia is perhaps the most fundamental expression of the Cenozoic Indo-Asian collision, yet an understanding of the timing and rates of development of the Tibetan Plateau remains elusive. Here we investigate the Cenozoic thermal histories of rocks along the eastern margin of the plateau adjacent to the Sichuan Basin in an effort to determine when the steep topographic escarpment that characterizes this margin developed. Temperaturetime paths inferred from 40 Ar/ 39 Ar thermochronology of biotite, multiple diffusion domain modeling of alkali feldspar 40 Ar release spectra, and (U-Th)/He thermochronology of zircon and apatite imply that rocks at the present-day topographic front of the plateau underwent slow cooling (<1°C/m.y.) from Jurassic times until the late Miocene or early Pliocene. The regional extent and consistency of thermal histories during this time period suggest the presence of a stable thermal structure and imply that regional denudation rates were low (<0.1 mm/yr for nominal continental geotherms). Beginning in the late Miocene or early Pliocene, these samples experienced a pronounced cooling event (>30°-50°C/m.y.) coincident with exhumation from inferred depths of $8 -10 km, at denudation rates of 1 -2 mm/yr. Samples from the interior of the plateau continued to cool relatively slowly during the same time period ($3°C/m.y.), suggesting limited exhumation (1 -2 km). However, these samples record a slight increase in cooling rate (from <1 to $3°C/m.y.) at some time during the middle Tertiary; the tectonic significance of this change remains uncertain. Regardless, late Cenozoic denudation in this region appears to have been markedly heterogeneous, with the highest rates of exhumation focused at the topographic front of the plateau margin. We infer that the onset of rapid cooling at the plateau margin reflects the erosional response to the development of regionally significant topographic gradients between the plateau and the stable Sichuan Basin and thus marks the onset of deformation related to the development of the Tibetan Plateau in this region. The present margin of the plateau adjacent to and north of the Sichuan Basin is apparently no older than the late Miocene or early Pliocene ($5 -12 Ma).

International audienceSamples from the Rocknest aeolian deposit were heated to ~835°C under helium flow and evolved gases analyzed by Curiosity's Sample Analysis at Mars instrument suite. H2O, SO2, CO2, and O2 were the major gases released. Water abundance (1.5 to 3 weight percent) and release temperature suggest that H2O is bound within an amorphous component of the sample. Decomposition of fine-grained Fe or Mg carbonate is the likely source of much of the evolved CO2. Evolved O2 is coincident with the release of Cl, suggesting that oxygen is produced from thermal decomposition of an oxychloride compound. Elevated δD values are consistent with recent atmospheric exchange. Carbon isotopes indicate multiple carbon sources in the fines. Several simple organic compounds were detected, but they are not definitively martian in origin